The OH and O-D stretching vibrations in the hydrates of sodium and potassium saccharinate : spectra-structure correlations

作者: G. Jovanovski , O. Grupče , B. Šoptrajanov

DOI: 10.1016/0022-2860(90)80032-F

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摘要: Abstract The infrared spectra of the two hydrates sodium saccharinate in region OH and O-D stretching vibrations protiated partially deuterated samples are considerably different. less stable monoclinic form is obviously a higher hydrate which easily converted into more triclinic one. observed frequencies for crystals correlated with crystallographically determined Ow⋯O Ow⋯N distances. compounds compared those potassium saccharinate.

参考文章(3)
G. Jovanovski, B. Šoptrajanov, Spectra-structure correlations in the isomorphous series of metal (II) saccharinates hexahydrates Journal of Molecular Structure. ,vol. 143, pp. 159- 162 ,(1986) , 10.1016/0022-2860(86)85228-0
Gligor Jovanovski, Bojan Šoptrajanov, Bonding of the carbonyl group in metal saccharinates : correlation with the infrared spectra Journal of Molecular Structure. ,vol. 174, pp. 467- 472 ,(1988) , 10.1016/0022-2860(88)80202-3