The kinetics of methanol oxidation on a supported silver catalyst
作者： D ROBB
DOI: 10.1016/0021-9517(74)90194-8
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摘要: Abstract The oxidation of methanol to formaldehyde on silver catalysts was studied at about 420 °C and atmospheric pressure in a fixed-bed differential reactor. reaction zero order oxygen except very low pressures, slightly less than first methanol, inhibited by the products. data can be fitted following equation, which is based competitive adsorption products sites formed reversible chemisorption adsorbed with underlying atoms: r = ( kK m P 1 + K p ) o 2 .
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