Syntheses of a stable tristibine and of related antimony compounds with the 2,6-dimesitylphenyl (Dmp) substituent

作者: HJ Breunig , E Lork , O Moldovan , CI Raţ , None

DOI: 10.1016/J.JORGANCHEM.2008.04.038

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摘要: DmpSbBr 2 (Dmp = 2,6-Mes C 6 H 3 ) ( 1 is obtained by the reaction of DmpMgBr with SbCl . The KI in ethanol gives DmpSbI ). Dmp(Ph)SbBr prepared from and PhSbCl Compound or react LiAlH 4 to form DmpSbH Dmp(Ph)SbH 5 reacts MeI presence DBU give Dmp(Me)SbH DmpSb(SbMe 7 Me Sb Elimination hydrogen [Dmp(Me)Sb] 8 Hydrolysis Dmp(Ph)SbOH 9 molecular structures – , were determined X-ray diffraction on single crystals.

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