Impacts of acidity and textural properties of oxidized carbon materials on their catalytic activity for hydrolysis of cellobiose

作者: Irina Delidovich , Regina Palkovits

DOI: 10.1016/J.MICROMESO.2015.07.011

关键词:

摘要: Abstract Hydrolysis of cellobiose was investigated in the presence oxidized carbon materials with different textural properties and concentrations surface acidic groups. Specifically, microporous activated carbon, graphite-like mesoporous Sibunit multi-walled nanotubes were studied. Catalytic activity found to correlate concentration sites. Activated HNO 3 at 130 °C exhibited superior catalytic due highest acidity this material. The performance predominantly dependent on acidity, while only played a minor role, no mass transfer limitations observed for catalysts.

参考文章(36)
Masaaki Kitano, Daizo Yamaguchi, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Shigenobu Hayashi, Michikazu Hara, None, Adsorption-Enhanced Hydrolysis of β-1,4-Glucan on Graphene-Based Amorphous Carbon Bearing SO3H, COOH, and OH Groups Langmuir. ,vol. 25, pp. 5068- 5075 ,(2009) , 10.1021/LA8040506
Mitsuru Sasaki, Zhen Fang, Yoshiko Fukushima, Tadafumi Adschiri, Kunio Arai, Dissolution and Hydrolysis of Cellulose in Subcritical and Supercritical Water Industrial & Engineering Chemistry Research. ,vol. 39, pp. 2883- 2890 ,(2000) , 10.1021/IE990690J
Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Daizo Yamaguchi, Hideki Kato, Shigenobu Hayashi, None, Hydrolysis of Cellulose by Amorphous Carbon Bearing SO3H, COOH, and OH Groups Journal of the American Chemical Society. ,vol. 130, pp. 12787- 12793 ,(2008) , 10.1021/JA803983H
Sebastian Osswald, Mickael Havel, Yury Gogotsi, Monitoring oxidation of multiwalled carbon nanotubes by Raman spectroscopy Journal of Raman Spectroscopy. ,vol. 38, pp. 728- 736 ,(2007) , 10.1002/JRS.1686
Jared Bourke, Merilyn Manley-Harris, Chihiro Fushimi, Kiyoshi Dowaki, Teppei Nunoura, Michael Jerry Antal, Do All Carbonized Charcoals Have the Same Chemical Structure? 2. A Model of the Chemical Structure of Carbonized Charcoal† Industrial & Engineering Chemistry Research. ,vol. 46, pp. 5954- 5967 ,(2007) , 10.1021/IE070415U
Li Shuai, Xuejun Pan, Hydrolysis of cellulose by cellulase-mimetic solid catalyst Energy and Environmental Science. ,vol. 5, pp. 6889- 6894 ,(2012) , 10.1039/C2EE03373A
Xiaochen Zhao, Jia Wang, Chengmeng Chen, Yanqiang Huang, Aiqin Wang, Tao Zhang, Graphene oxide for cellulose hydrolysis: how it works as a highly active catalyst? Chemical Communications. ,vol. 50, pp. 3439- 3442 ,(2014) , 10.1039/C3CC49634A
Pierre Gallezot, Conversion of biomass to selected chemical products Chemical Society Reviews. ,vol. 41, pp. 1538- 1558 ,(2012) , 10.1039/C1CS15147A
I. Delidovich, K. Leonhard, R. Palkovits, Cellulose and hemicellulose valorisation: an integrated challenge of catalysis and reaction engineering Energy and Environmental Science. ,vol. 7, pp. 2803- 2830 ,(2014) , 10.1039/C4EE01067A
Kiichi Fukuhara, Kiyotaka Nakajima, Masaaki Kitano, Hideki Kato, Shigenobu Hayashi, Michikazu Hara, None, Structure and Catalysis of Cellulose‐Derived Amorphous Carbon Bearing SO3H Groups Chemsuschem. ,vol. 4, pp. 778- 784 ,(2011) , 10.1002/CSSC.201000431