Structure of Glass‐Forming Halides. II. Liquid Zinc Chloride
作者： J. D. Mackenzie , W. K. Murphy
DOI: 10.1063/1.1731151
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摘要: Measurements of viscosity and electric conductivity in liquid zinc chloride indicate that at temperatures near the melting point, melt is associated. The degree association diminishes rapidly with increasing temperature as shown by decreasing energies activation for both viscous flow conduction. Liquid ZnCl2 thus not a normal fused salt such CdCl2 or MgCl2. From crystal structure Raman absorption spectra, mechanism fusion are postulated. ease glass formation discussed terms structure.
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