Hybridization: A Chemical Bonding Nature of Atoms

作者: Dongfeng Xue , Congting Sun , Xiaoyan Chen

DOI: 10.1002/CJOC.201700425

关键词:

摘要: … For the transition metals in IIIB - VIIIB groups, gradually increased number of valence electrons in d orbitals leads to the decreased number of d orbitals in hybridization and decreased …

参考文章(36)
P. Strange, A. Svane, W. M. Temmerman, Z. Szotek, H. Winter, Understanding the valency of rare earths from first-principles theory Nature. ,vol. 399, pp. 756- 758 ,(1999) , 10.1038/21595
Flor de María Ramírez, Tania Tosheva, Emil Tashev, Eduardo García-Villafaña, Stoycho Shenkov, Sabi Varbanov, Synthesis of a para-tert-octylcalix[4]arene fitted with phosphinoyl pendant arms and its complexation properties towards f-elements Polyhedron. ,vol. 56, pp. 123- 133 ,(2013) , 10.1016/J.POLY.2013.04.003
Ronald J. Gillespie, James N. Spencer, Richard S. Moog, Bonding and Molecular Geometry without Orbitals - The Electron Domain Model Journal of Chemical Education. ,vol. 73, pp. 622- 627 ,(1996) , 10.1021/ED073P622
Keyan Li, Xingtao Wang, Fangfang Zhang, Dongfeng Xue, Electronegativity identification of novel superhard materials. Physical Review Letters. ,vol. 100, pp. 235504- 235504 ,(2008) , 10.1103/PHYSREVLETT.100.235504
Virginie Lemierre, Anna Chrostowska, Alain Dargelos, Henry Chermette, Calculation of Ionization Potentials of Small Molecules: A Comparative Study of Different Methods Journal of Physical Chemistry A. ,vol. 109, pp. 8348- 8355 ,(2005) , 10.1021/JP050254C
Werner Kutzelnigg, Chemical Bonding in Higher Main Group Elements Angewandte Chemie. ,vol. 23, pp. 272- 295 ,(1984) , 10.1002/ANIE.198402721
Keyan Li, Dongfeng Xue, Estimation of Electronegativity Values of Elements in Different Valence States Journal of Physical Chemistry A. ,vol. 110, pp. 11332- 11337 ,(2006) , 10.1021/JP062886K
Alexandre Quemet, Rene Brennetot, Jean-Yves Salpin, Alvaro Cimas, Colin Marsden, Jeanine Tortajada, Pierre Vitorge, How Can f-Block Monocations Behave as Monocations of d-Block Transition Metals? European Journal of Inorganic Chemistry. ,vol. 2012, pp. 3551- 3555 ,(2012) , 10.1002/EJIC.201200455
Alan E. Reed, Frank. Weinhold, On the role of d orbitals in sulfur hexafluoride Journal of the American Chemical Society. ,vol. 108, pp. 3586- 3593 ,(1986) , 10.1021/JA00273A006