Functionalized Polyethylene Synthesis Via ADMET Chemistry

摘要: for more than fifty years now, synthetic chemist have sought to make functionalized polyethylene via transition metal catalyzed polymerization. Such catalytic routes offer the promise of microstructural control that has not been achieved with current free radical techniques, and could significantly broaden utility range properties these polymers. Unfortunately, use available complexes precluded by their susceptibility poisoning heteroatoms [1]. However, recent research Brookhart