Quality and stability of compound indium sulphide as source material for buffer layers in Cu(In,Ga)Se2 solar cells
作者： Paul Pistor , Raquel Caballero , Dimitrios Hariskos , Victor Izquierdo-Roca , Rolf Wächter
DOI: 10.1016/J.SOLMAT.2008.09.015
关键词:
摘要: Abstract Indium sulphide layers were deposited by thermal evaporation from compound In 2 S 3 powder provided different suppliers. The source material quality was systematically analysed in terms of contamination, stoichiometry, grain size, behaviour and crystallinity. It found to vary significantly for influence stability on layer growth properties investigated various optical, crystallographic surface analysis methods. findings correlated with the performance solar cells prepared an buffer layer. This includes jV-curves quantum efficiencies Cu ( , Ga ) Se absorbers. After a post annealing step air, best reached certified efficiency 15.2% remarkably high fill factor (75.6%) open circuit voltage (677 mV).
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L. Aldon, M. Uhrmacher, C. Branci, L. Ziegeler, J. Roth, P. Schaaf, H. Metzner, J. Olivier-Fourcade, J. C. Jumas, PERTURBED ANGULAR CORRELATION STUDY OF THE THIOSPINEL BETA -IN2S3 Physical Review B. ,vol. 58, pp. 11303- 11312 ,(1998) , 10.1103/PHYSREVB.58.11303
N. Barreau, J.C. Bernède, S. Marsillac, Study of the new β-In2S3 containing Na thin films. Part II: Optical and electrical characterization of thin films Journal of Crystal Growth. ,vol. 241, pp. 51- 56 ,(2002) , 10.1016/S0022-0248(02)01243-5
A Yu Zavrazhnov, AV Naumov, PV Anorov, EG Goncharov, VI Sidei, VS Pervov, None, T - x Phase Diagram of the In-S System Inorganic Materials. ,vol. 42, pp. 1294- 1298 ,(2006) , 10.1134/S0020168506120028
N. Naghavi, S. Spiering, M. Powalla, B. Cavana, D. Lincot, High-efficiency copper indium gallium diselenide (CIGS) solar cells with indium sulfide buffer layers deposited by atomic layer chemical vapor deposition (ALCVD) Progress in Photovoltaics. ,vol. 11, pp. 437- 443 ,(2003) , 10.1002/PIP.508
R. Diehl, R. Nitsche, Vapour growth of three In2S3 modifications by iodine transport Journal of Crystal Growth. ,vol. 28, pp. 306- 310 ,(1975) , 10.1016/0022-0248(75)90067-6
Alan R. Miller, Alan W. Searcy, Thermodynamic Stabilities as a Function of Composition for Indium Sulfide Phases from Mass Spectrometer Intensity vs. Time Data1 The Journal of Physical Chemistry. ,vol. 69, pp. 3826- 3832 ,(1965) , 10.1021/J100895A031
Alan R. Miller, Alan W. Searcy, THE SUBLIMATION OF INDIUM SESQUISULFIDE1 The Journal of Physical Chemistry. ,vol. 67, pp. 2400- 2404 ,(1963) , 10.1021/J100805A034
Daniela Ferro, Vincenzo Piacente, Paolo Scardala, Sublimation behaviour of indium trisulphide studied by a simultaneous torsion and Knudsen technique Journal of Materials Science Letters. ,vol. 7, pp. 1301- 1304 ,(1988) , 10.1007/BF00719964
A. Strohm, L. Eisenmann, R.K. Gebhardt, A. Harding, T. Schlötzer, D. Abou-Ras, H.W. Schock, ZnO/InxSy/Cu(In,Ga)Se2 solar cells fabricated by coherent heterojunction formation Thin Solid Films. ,vol. 480, pp. 162- 167 ,(2005) , 10.1016/J.TSF.2004.11.032
N. A. Allsop, A. Schönmann, H.-J. Muffler, M. Bär, M. C. Lux-Steiner, Ch.-H. Fischer, Spray-ILGAR indium sulfide buffers for Cu(In,Ga)(S,Se)2 solar cells Progress in Photovoltaics. ,vol. 13, pp. 607- 616 ,(2005) , 10.1002/PIP.655