Synthesis, characterization, and crystal structure of platinum(II) and palladium(II) chlorides with an acidic α-diimine ligand
作者： Brian P. Buffin , Abhijit Kundu
DOI: 10.1016/S1387-7003(03)00082-0
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摘要: Abstract Reaction of the symmetrical α-diimine ligand L with either PtCl2 or PdCl2(C6H5CN)2 affords square planar d8 complexes 1 and 2, respectively. Both were characterized by NMR spectroscopy elemental analysis. The solid-state structure 1, which crystallized in triclinic space group P unit cell parameters a=8.688(2) A , b=13.840(2) c=14.136(2) α=111.346(14)°, β=103.82(2)°, γ=102.69(2)°, was established X-ray crystallography.
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Henk Van der Poel, Gerard Van Koten, Kees Vrieze, Novel bonding modes of a-diimines. Synthesis and characterization of [MCl2L(a-diimine)] and [MCl2(a-diimine)n] (M = Pd, Pt; L = phosphine or arsine; n = 1, 2) containing s,s-N,N, sN, or s-N´´sN, bonded a-diimines Inorganic Chemistry. ,vol. 19, pp. 1145- 1151 ,(1980) , 10.1021/IC50207A008
Robert J. Angelici, Synthesis and technique in inorganic chemistry ,(1969)
Henk. Van der Poel, Gerard. Van Koten, Five-coordinate [PtIICl2(h2-olefin)L2] (L2 = s,s-N,N' bonded a-diimine or N,N'-disubstituted-1,2-diaminoethane) complexes. Solution conformation, h2-olefin rotational barriers (NMR) and X-ray molecular structure of [PtCl2(h2-styrene) (t-Bu-N=CHCH=N=t-Bu)] Inorganic Chemistry. ,vol. 20, pp. 2941- 2950 ,(1981) , 10.1021/IC50223A038
Nadia M. Comerlato, Geraldo L. Crossetti, R. Alan Howie, Pollyanna C. D. Tibultino, James L. Wardell, Dichloro[N,N′-bis(2,6-diisopropylphenyl)-1,2-ethanediimine-N,N′]palladium Acta Crystallographica Section E-structure Reports Online. ,vol. 57, ,(2001) , 10.1107/S1600536801008704
Gerard Van Koten, Kees Vrieze, 1,4-Diaza-1,3-butadiene (a-diimine) ligands: their coordination modes and the reactivity of their metal complexes Advances in Organometallic Chemistry. ,vol. 21, pp. 151- 239 ,(1982) , 10.1016/S0065-3055(08)60380-9
Ruud van Belzen, René A. Klein, Wilberth J. J. Smeets, Anthony L. Spek, Roland Benedix, Cornells J. Elsevier, Synthesis and characterization of 9,10‐bis(arylimino)‐9,10‐dihydrophenanthrenes, the structure of (Z,Z)‐9,10‐bis(phenylimino)‐9,10‐dihydrophenanthrene and PdCl2‐[(E,E)‐9,10‐bis(phenylimino)‐9,10‐dihydrophenanthrene] in the solid state and in solution Recueil des Travaux Chimiques des Pays-Bas. ,vol. 115, pp. 275- 285 ,(1996) , 10.1002/RECL.19961150504
Abhijit Kundu, Brian P. Buffin, Aqueous Organometallic Chemistry with Nitrogen Ligands: Synthesis of Hydrophilic Platinum(0) Olefin Complexes Organometallics. ,vol. 20, pp. 3635- 3637 ,(2001) , 10.1021/OM010212K
Lars Johansson, Olav B. Ryan, Christian Rømming, Mats Tilset, Redox Chemistry of Dimethylplatinum(II) Diimine Complexes. Oxidatively Induced Pt−Me Transfer between Transient Platinum(III) Cation Radicals Organometallics. ,vol. 17, pp. 3957- 3966 ,(1998) , 10.1021/OM9801498
Steven D. Ittel, Lynda K. Johnson, Maurice Brookhart, Late-metal catalysts for ethylene homo- and copolymerization. Chemical Reviews. ,vol. 100, pp. 1169- 1204 ,(2000) , 10.1021/CR9804644
Kaiyuan Yang, Rene J. Lachicotte, Richard Eisenberg, Unsymmetrical 1,4-Diazabutadiene Complexes of Platinum(II) Organometallics. ,vol. 16, pp. 5234- 5243 ,(1997) , 10.1021/OM970452T