Rotational band contour analysis in the Ã1A′-[Xtilde]1A′ electronic systems of substituted naphthalenes
作者： J.M. Hollas , S.N. Thakur
DOI: 10.1080/00268977400100921
关键词:
摘要: The 00 0 bands of the A 1 A′-[Xtilde] A′ systems 1-fluoro, 1-hydroxy and 1-aminonaphthalene have been investigated by rotational band contour analysis. in 1-fluoro 1-hydroxynaphthalene are 70 per cent type 30 B, 75 25 B hybrids respectively: electronic transition moment vector has rotated about 15° towards carbon atom C3 F OH substituents compared to naphthalene (in which, A-[Xtilde] system, it is along long in-plane axis). In seems likely that predominantly A, but could not be observed with sufficient intensity able obtain excited state constants any certainty.
harvard.edu
sci-hub.se 参考文章(11)
H.D. Bist, J.C.D. Brand, D.R. Williams, The 2750-Å band system of phenol Journal of Molecular Spectroscopy. ,vol. 24, pp. 413- 467 ,(1967) , 10.1016/0022-2852(67)90105-1
Yoshié Tanizaki, Séi-ichi Kubodera, Dichroism analysis Journal of Molecular Spectroscopy. ,vol. 24, pp. 1- 18 ,(1967) , 10.1016/0022-2852(67)90064-1
Kirk H. Michaelian, Stanley M. Ziegler, Vibrational Spectra and Assignments for Series of Mono- and Dihalonaphthalenes Applied Spectroscopy. ,vol. 27, pp. 13- 21 ,(1973) , 10.1366/000370273774333966
John C.D. Brand, Denis R. Williams, Thomas J. Cook, Vibrational analysis of the first ultraviolet band system of aniline Journal of Molecular Spectroscopy. ,vol. 20, pp. 359- 380 ,(1966) , 10.1016/0022-2852(66)90008-7
T. Cvitaš, J.M. Hollas, G.H. Kirby, Interpretation of rotational constants of the first singlet excited state of substituted benzenes in terms of molecular geometry Molecular Physics. ,vol. 19, pp. 305- 316 ,(1970) , 10.1080/00268977000101311
Rotational Band Contours in Electronic Spectra of Large Asymmetric Top Molecules: The 2750 Å System of Phenol Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 307, pp. 97- 110 ,(1968) , 10.1098/RSPA.1968.0177
J.M. Hollas, S.N. Thakur, Rotational band contour analysis in the 3120 Å system of naphthalene Molecular Physics. ,vol. 22, pp. 203- 212 ,(1971) , 10.1080/00268977100102481
Kichisuke. Nishimoto, ELECTRONIC SPECTRA AND STRUCTURE OF - AND -NAPHTHOL The Journal of Physical Chemistry. ,vol. 67, pp. 1443- 1446 ,(1963) , 10.1021/J100801A009
J.M. Hollas, S.N. Thakur, Rotational band contour analysis in the à 1 A′-[Xtilde] 1 A′ electronic systems of substituted naphthalenes: I. 2-Fluoro-, 2-hydroxy- and 2-aminonaphthalene Molecular Physics. ,vol. 25, pp. 1315- 1334 ,(1973) , 10.1080/00268977300101151
Kichisuke Nishimoto, Electron interaction in molecules Theoretical Chemistry Accounts. ,vol. 7, pp. 207- 219 ,(1967) , 10.1007/BF01045578