Abraham model enthalpy of solvation correlations for solutes dissolved in 1-alkanol solvents (C4–C6)

作者: Heidi Zettl , Michael H. Abraham , William E. Acree , Damini Grover , Erin Hart

DOI: 10.1080/00319104.2015.1018259

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摘要: Experimental data have been compiled from the published literature pertaining to enthalpies of solvation inorganic gases and organic solutes dissolved in 1-butanol, 1-pentanol 1-hexanol at 298 K. It is shown that Abraham model can be used satisfactorily correlate measured within standard deviations 2.86 kJ/mole for 131 points, 2.67 kJ/mole 92 points 2.89 kJ/mole 84 respectively. The derived equations were validated by training set test analyses.

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