Comparative thermal stability of carbon intercalation anodes and lithium metal anodes for rechargeable lithium batteries

作者: Ulrich von Sacken , Eric Nodwell , Avtar Sundher , J.R. Dahn

DOI: 10.1016/0378-7753(94)02076-F

关键词:

摘要: Abstract An accelerating rate calorimeter has been used to probe the thermal stability of LixC6 in electrolyte as a function specific surface area, lithium content, and solvent choice. The exotherm can be qualitatively modelled based on reaction which produces passivating film carbon surface.

参考文章(5)
D. Fouchard, L. Lechner, Analysis of safety and reliability in secondary lithium batteries Electrochimica Acta. ,vol. 38, pp. 1193- 1198 ,(1993) , 10.1016/0013-4686(93)80049-6
Z. X. Shu, R. S. McMillan, J. J. Murray, Electrochemical Intercalation of Lithium into Graphite Journal of The Electrochemical Society. ,vol. 140, pp. 922- 927 ,(1993) , 10.1149/1.2056228
D.I. Townsend, J.C. Tou, Thermal hazard evaluation by an accelerating rate calorimeter Thermochimica Acta. ,vol. 37, pp. 1- 30 ,(1980) , 10.1016/0040-6031(80)85001-5
D. Aurbach, M. L. Daroux, P. W. Faguy, E. Yeager, Identification of surface films formed on lithium in propylene carbonate solutions Journal of The Electrochemical Society. ,vol. 134, pp. 1611- 1620 ,(1987) , 10.1149/1.2100722