Methanol synthesis over a Zn-deposited copper model catalyst

作者: J. Nakamura , I. Nakamura , T. Uchijima , Y. Kanai , T. Watanabe

DOI: 10.1007/BF00808596

关键词:

摘要: … to formation of a Cu+-O-Zn active site. To prove the proposed … Cu surface was estimated by XPS assuming that the oxygen … Zn 2p3/2 XPS intensity ratio using their XPS sensitivity factors…

参考文章(15)
T. Fujitani, M. Saito, Y. Kanai, T. Kakumoto, T. Watanabe, J. Nakamura, T. Uchijima, The role of metal oxides in promoting a copper catalyst for methanol synthesis Catalysis Letters. ,vol. 25, pp. 271- 276 ,(1994) , 10.1007/BF00816307
Charles T. Campbell, Karen A. Daube, J.M. White, Cu/ZnO(0001̄) and ZnOx/Cu(111): Model catalysts for methanol synthesis Surface Science. ,vol. 182, pp. 458- 476 ,(1987) , 10.1016/0039-6028(87)90013-6
P. B. Rasmussen, P. M. Holmblad, T. Askgaard, C. V. Ovesen, P. Stoltze, J. K. N�rskov, I. Chorkendorff, Methanol synthesis on Cu(100) from a binary gas mixture of CO2 and H2 Catalysis Letters. ,vol. 26, pp. 373- 381 ,(1994) , 10.1007/BF00810611
J�nos Szanyi, D. Wayne Goodman, Methanol synthesis on a Cu(100) catalyst Catalysis Letters. ,vol. 10, pp. 383- 390 ,(1991) , 10.1007/BF00769173
Godfrey C. Chinchen, Michael S. Spencer, Kenneth C. Waugh, David A. Whan, Promotion of methanol synthesis and the water-gas shift reactions by adsorbed oxygen on supported copper catalysts Journal of the Chemical Society, Faraday Transactions. ,vol. 83, pp. 2193- 2212 ,(1987) , 10.1039/F19878302193
Stephen V. Didziulis, Kristine D. Butcher, Susan L. Cohen, Edward I. Solomon, Chemistry of copper overlayers on zinc oxide single-crystal surfaces: model active sites for copper/zinc oxide methanol synthesis catalysts Journal of the American Chemical Society. ,vol. 111, pp. 7110- 7123 ,(1989) , 10.1021/JA00200A033
A. Ludviksson, K.H. Ernst, R. Zhang, C.T. Campbell, The Chemisorption of CO on Cu Films on ZnO(0001)-O Journal of Catalysis. ,vol. 141, pp. 380- 388 ,(1993) , 10.1006/JCAT.1993.1148
Y. Kanai, T. Watanabe, T. Fujitani, M. Saito, J. Nakamura, T. Uchijima, Evidence for the migration of ZnOx in a Cu/ZnO methanol synthesis catalyst Catalysis Letters. ,vol. 27, pp. 67- 78 ,(1994) , 10.1007/BF00806979
Robert Burch, Stanislaw E. Golunski, Michael S. Spencer, The role of copper and zinc oxide in methanol synthesis catalysts Journal of the Chemical Society, Faraday Transactions. ,vol. 86, pp. 2683- 2691 ,(1990) , 10.1039/FT9908602683
J.C.J. Bart, R.P.A. Sneeden, Copper-Zinc Oxide-Alumina Methanol Catalysts Revisited Catalysis Today. ,vol. 2, pp. 1- 124 ,(1987) , 10.1016/0920-5861(87)80001-9