Ternary adsorption equilibrium of H2/CH4/C2H4 onto activated carbon

作者: B JEONG , E AHN , J YUN , C LEE , D CHOI

DOI: 10.1016/J.SEPPUR.2006.11.004

关键词:

摘要: Abstract Adsorption equilibrium data for the pure component H 2 , CH 4 and C their binary ternary mixtures have been measured on activated carbon. The experimental measurements were done by a static method in pressures up to 2 MPa at temperatures of 293.15, 303.15, 313.15 K. Langmuir, Langmuir–Freundlich (L–F), Flory–Huggins vacancy solution model (F–H VSM) used correlate isotherm data. It was found that L–F F–H VSM show better fitting accuracy than other models. Mixture adsorption carbon predicted extended L–F, ideal adsorbed theory (IAST), (VSM).

参考文章(25)
R. Staudt, F. Dreisbach, J.U. Keller, Correlation and Calculation of Multicomponent Adsorption Equilibria Data Using a Generalized Adsorption Isotherm Adsorption-journal of The International Adsorption Society. ,vol. 4, pp. 57- 62 ,(1998) , 10.1023/A:1008887320311
F. Dreisbach, R. Staudt, J.U. Keller, High Pressure Adsorption Data of Methane, Nitrogen, Carbon Dioxide and their Binary and Ternary Mixtures on Activated Carbon Adsorption-journal of The International Adsorption Society. ,vol. 5, pp. 215- 227 ,(1999) , 10.1023/A:1008914703884
Alan L. Myers, Diego P. Valenzuela, Adsorption equilibrium data handbook ,(1989)
Navid Mostoufi, Alkis Constantinides, Numerical Methods for Chemical Engineers With Matlab Applications ,(1999)
Chuncai Yao, Extended and improved Langmuir equation for correlating adsorption equilibrium data Separation and Purification Technology. ,vol. 19, pp. 237- 242 ,(2000) , 10.1016/S1383-5866(00)00060-5
Manuela Serban, Michele A. Lewis, Christopher L. Marshall, Richard D. Doctor, Hydrogen Production by Direct Contact Pyrolysis of Natural Gas Energy & Fuels. ,vol. 17, pp. 705- 713 ,(2003) , 10.1021/EF020271Q
A. Ahmadpour, K. Wang, D. D. Do, Comparison of models on the prediction of binary equilibrium data of activated carbons Aiche Journal. ,vol. 44, pp. 740- 752 ,(1998) , 10.1002/AIC.690440322
Solot Suwanayuen, Ronald P. Danner, A gas adsorption isotherm equation based on vacancy solution theory AIChE Journal. ,vol. 26, pp. 68- 76 ,(1980) , 10.1002/AIC.690260112