SAPO-34 coated adsorbent heat exchanger for adsorption chillers

作者: Angelo Freni , Lucio Bonaccorsi , Luigi Calabrese , Angela Caprì , Andrea Frazzica

DOI: 10.1016/J.APPLTHERMALENG.2015.02.052

关键词:

摘要: Abstract In this work, adsorbent coatings on aluminum surfaces were prepared by dip-coating method starting from a water suspension of SAPO-34 zeolite and silane-based binder. Silane-zeolite morphology surface coverage grade evaluated scanning electron microscopy. Adhesive mechanical properties peel, pull-off, impact micro-hardness tests, confirming the good interaction between metal substrate, binder zeolite. Adsorption equilibrium kinetics vapour adsorption coating studied in range T = 30–150 °C pH2O = 11 mbar using CAHN 2000 thermo-balance. It was found that, investigated conditions, organic doesn't affect capacity original Subsequently, applied finned flat-tubes heat exchanger realizing full-scale AdHEx with an uniform 0.1 mm thick metal/adsorbent mass ratio = 6. The cooling realized coated measured lab-scale chiller under realistic operating conditions for air conditioning applications. produced up to 675 W/kgads specific power cycle time 5 min. stability adsorber subjected 600 sorption cycles successfully verified.

参考文章(26)
Bell Reuben H, Foley Kevin M, Silane coupling agents ,(1974)
Jorg Kärger, Douglas M. Ruthven, Diffusion in Zeolites and Other Microporous Solids ,(1992)
A. Freni, F. Russo, S. Vasta, M. Tokarev, Yu.I. Aristov, G. Restuccia, An advanced solid sorption chiller using SWS-1L Applied Thermal Engineering. ,vol. 27, pp. 2200- 2204 ,(2007) , 10.1016/J.APPLTHERMALENG.2005.07.023
Melkon Tatlıer, Ayşe Erdem-Şenatalar, The effects of thermal and mass diffusivities on the performance of adsorption heat pumps employing zeolite synthesized on metal supports Microporous and Mesoporous Materials. ,vol. 28, pp. 195- 203 ,(1999) , 10.1016/S1387-1811(98)00301-1
R.E. Critoph, Solid sorption cycles: A short history International Journal of Refrigeration-revue Internationale Du Froid. ,vol. 35, pp. 490- 493 ,(2012) , 10.1016/J.IJREFRIG.2012.02.007
A. L. Correa-Borroel, S. Gutierrez, E. Arce, R. Cabrera-Sierra, P. Herrasti, Organosilanes and polypyrrole as anticorrosive treatment of aluminium 2024 Journal of Applied Electrochemistry. ,vol. 39, pp. 2385- 2395 ,(2009) , 10.1007/S10800-009-9925-Z
Francis Meunier, Adsorption heat powered heat pumps Applied Thermal Engineering. ,vol. 61, pp. 830- 836 ,(2013) , 10.1016/J.APPLTHERMALENG.2013.04.050
Alessio Sapienza, Salvatore Santamaria, Andrea Frazzica, Angelo Freni, Influence of the management strategy and operating conditions on the performance of an adsorption chiller Energy. ,vol. 36, pp. 5532- 5538 ,(2011) , 10.1016/J.ENERGY.2011.07.020
Lucio Bonaccorsi, Edoardo Proverbio, Angelo Freni, Giovanni Restuccia, In situ Growth of Zeolites on Metal Foamed Supports for Adsorption Heat Pumps Journal of Chemical Engineering of Japan. ,vol. 40, pp. 1307- 1312 ,(2007) , 10.1252/JCEJ.07WE174