Sodium ion insertion in hollow carbon nanowires for battery applications.

作者: Yuliang Cao , Lifen Xiao , Maria L. Sushko , Wei Wang , Birgit Schwenzer

DOI: 10.1021/NL3016957

关键词:

摘要: Hollow carbon nanowires (HCNWs) were prepared through pyrolyzation of a hollow polyaniline nanowire precursor. The HCNWs used as anode material for Na-ion batteries deliver a high reversible capacity of 251 mAh g–1 and 82.2% capacity retention over 400 charge–discharge cycles between 1.2 and 0.01 V (vs Na+/Na) at a constant current of 50 mA g–1 (0.2 C). Excellent cycling stability is also observed at an even higher charge–discharge rate. A high reversible capacity of 149 mAh g–1 also can be obtained at a current rate of 500 …

参考文章(38)
J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries Nature. ,vol. 414, pp. 359- 367 ,(2001) , 10.1038/35104644
R. Alcántara, F.J. Fernández Madrigal, P. Lavela, J.L. Tirado, J.M. Jiménez Mateos, C. Gómez de Salazar, R. Stoyanova, E. Zhecheva, Characterisation of mesocarbon microbeads (MCMB) as active electrode material in lithium and sodium cells Carbon. ,vol. 38, pp. 1031- 1041 ,(2000) , 10.1016/S0008-6223(99)00215-8
Ricardo Alcántara, Juan M. Jiménez-Mateos, Pedro Lavela, José L. Tirado, Carbon black: a promising electrode material for sodium-ion batteries Electrochemistry Communications. ,vol. 3, pp. 639- 642 ,(2001) , 10.1016/S1388-2481(01)00244-2
Lifen Xiao, Yuliang Cao, Jie Xiao, Birgit Schwenzer, Mark H. Engelhard, Laxmikant V. Saraf, Zimin Nie, Gregory J. Exarhos, Jun Liu, A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes for Lithium‐Sulfur Batteries with Long Cycle Life Advanced Materials. ,vol. 24, pp. 1176- 1181 ,(2012) , 10.1002/ADMA.201103392
Guang-Yu Zhao, Hu-Lin Li, Preparation of polyaniline nanowire arrayed electrodes for electrochemical supercapacitors Microporous and Mesoporous Materials. ,vol. 110, pp. 590- 594 ,(2008) , 10.1016/J.MICROMESO.2007.06.023
Colin D. Wessells, Sandeep V. Peddada, Robert A. Huggins, Yi Cui, Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries Nano Letters. ,vol. 11, pp. 5421- 5425 ,(2011) , 10.1021/NL203193Q
Shinichi Komaba, Wataru Murata, Toru Ishikawa, Naoaki Yabuuchi, Tomoaki Ozeki, Tetsuri Nakayama, Atsushi Ogata, Kazuma Gotoh, Kazuya Fujiwara, Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries Advanced Functional Materials. ,vol. 21, pp. 3859- 3867 ,(2011) , 10.1002/ADFM.201100854
Michael E. Spahr, Hilmi Buqa, Andreas Würsig, Dietrich Goers, Laurence Hardwick, Petr Novák, Frank Krumeich, Joseph Dentzer, Cathie Vix-Guterl, Surface reactivity of graphite materials and their surface passivation during the first electrochemical lithium insertion Journal of Power Sources. ,vol. 153, pp. 300- 311 ,(2006) , 10.1016/J.JPOWSOUR.2005.05.032
Yuliang Cao, Lifen Xiao, Xinping Ai, Hanxi Yang, Surface-modified graphite as an improved intercalating anode for lithium-ion batteries Electrochemical and Solid State Letters. ,vol. 6, ,(2003) , 10.1149/1.1534730
B. L. Ellis, W. R. M. Makahnouk, Y. Makimura, K. Toghill, L. F. Nazar, A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries Nature Materials. ,vol. 6, pp. 749- 753 ,(2007) , 10.1038/NMAT2007