The reaction of diazomethane with double bonds—I

作者: M. Algueró , J. Bosch , J. Castañer , J. Castellá , J. Castells

DOI: 10.1016/S0040-4020(01)99293-2

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摘要: Abstract The reaction of α-carbomethoxy-γ-benzylidenebutenolide with diazomethane has been studied, and the β-methylbutenolide structure resulting product established through degradative synthetic work. Extension this direct C-methylation to other related butenolides is presented. Hydrogenation enol lactones discussed in some detail.

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