Algebraic expressions for vibration-rotation line intensities of near prolate asymmetric molecules: Application to SO2 molecule

作者: C. Secroun , A. Barbe , P. Jouve

DOI: 10.1016/0022-4073(73)90046-0

关键词:

摘要: Abstract A treatment of the intensities vibration-rotation lines near prolate asymmetric molecules is given, leading to explicit expressions relating observed appropriate coefficients in expansions potential energy and dipole moment. The theoretical results are compared with experimental determinations line υ 1 -band sulfur dioxide.

参考文章(14)
C. Secroun, A. Barbe, P. Jouve, Higher-order vibration intensities of polyatomic molecules: Application to diatomic and bent XY2 molecules Journal of Molecular Spectroscopy. ,vol. 45, pp. 1- 9 ,(1973) , 10.1016/0022-2852(73)90170-7
Gilbert Amat, Harald H. Nielsen, Ginette Tarrago, W. E. Blass, Rotation-Vibration of Polyatomic Molecules American Journal of Physics. ,vol. 40, pp. 1188- 1188 ,(1972) , 10.1119/1.1986798
David R. Lide, A Note on Rotational Line Strengths in Slightly Asymmetric Rotors The Journal of Chemical Physics. ,vol. 20, pp. 1761- 1763 ,(1952) , 10.1063/1.1700284
Edwin K. Gora, Simplified methods for the computation of asymmetric rotor energy levels and line strengths Journal of Molecular Spectroscopy. ,vol. 2, pp. 259- 272 ,(1958) , 10.1016/0022-2852(58)90079-1
N. Legay-Sommaire, F. Legay, Intensities of vibration-rotation lines for linear molecules of the type X-Y-Z Journal of Molecular Spectroscopy. ,vol. 8, pp. 1- 8 ,(1962) , 10.1016/0022-2852(62)90001-2
Daniel Kivelson, The Determination of the Potential Constants of SO2 from Centrifugal Distortion Effects The Journal of Chemical Physics. ,vol. 22, pp. 904- 908 ,(1954) , 10.1063/1.1740213
A.H. Nielsen, R.D. Shelton, W.H. Fletcher, Le spectre infrarouge et les constantes moléculaires de l'anhydride sulfureux Journal De Physique Et Le Radium. ,vol. 15, pp. 604- 607 ,(1954) , 10.1051/JPHYSRAD:01954001507-9060400
Harvey M. Hanson, Harald H. Nielsen, Intensities of rotation lines in absorption bands for symmetric molecules of the type AB ⋯ XYZ3 Journal of Molecular Spectroscopy. ,vol. 4, pp. 468- 476 ,(1960) , 10.1016/0022-2852(60)90109-0
J. H. Van Vleck, The Coupling of Angular Momentum Vectors in Molecules Reviews of Modern Physics. ,vol. 23, pp. 213- 227 ,(1951) , 10.1103/REVMODPHYS.23.213