The Interaction of Zinc(II) and Hydroxamic Acids and a Metal-Triggered Lossen Rearrangement
作者： Lucie DuchácÌková , Jana Roithová
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摘要: The structure and reactivity of a complex zinc(II), water, acetic acid, acetohydroxamic in which one the acids is deprotonated, investigated by means mass spectrometry, labeling studies, density functional calculations to unravel exceptional binding properties hydroxamic towards zinc-containing enzymes at molecular level. It shown that acid deprotonated complex, whereas present its neutral form. energies ligands zinc increase following order: water
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