Reactions of silanes with the binuclear hydride [[(Me2CH)2PCH2CH2P(CHMe2)2Rh]2(.mu.-H)2. Catalytic deuterium exchange on diphenylsilane and x-ray structure of [[(Me2CH)2PCH2CH2P(CHMe2)2]Rh]2(.mu.-H)(.mu.-.eta.2-HSiPh2)

作者： Michael D. Fryzuk , Lisa. Rosenberg , Steven J. Rettig

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摘要: … these binuclear derivatives are reported to be active in catalytic oligomerization.… binuclear metal hydrides, it was of interestto examine the reaction of silanes with a preformed binuclear …

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Reactions of silanes with the binuclear hydride [[(Me2CH)2PCH2CH2P(CHMe2)2Rh]2(.mu.-H)2. Catalytic deuterium exchange on diphenylsilane and x-ray structure of [[(Me2CH)2PCH2CH2P(CHMe2)2]Rh]2(.mu.-H)(.mu.-.eta.2-HSiPh2)

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Reactions of silanes with the binuclear hydride [[(Me2CH)2PCH2CH2P(CHMe2)2Rh]2(.mu.-H)2. Catalytic deuterium exchange on diphenylsilane and x-ray structure of [[(Me2CH)2PCH2CH2P(CHMe2)2]Rh]2(.mu.-H)(.mu.-.eta.2-HSiPh2)

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