ESR study of a bromine‐containing radical in γ‐irradiated bromomalonamide
作者： R. F. Picone , Max T. Rogers
DOI: 10.1063/1.1681807
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摘要: Both powder and single‐crystal ESR spectra of two paramagnetic species formed by γ‐irradiation bromomalonamide at 77°K have been obtained. One radical shows a large bromine hyperfine interaction plus small proton the g, A(81Br) e2qQ(81Br) tensors determined from an analysis deuterated form. The data interpreted as favoring structure · CHBrCONH2 for this species. second fragment has identified CONH2, but parameters are not reported since it studied previously. Neither is stable room temperature in host crystal.
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