Homolytic bond dissociation energies for the cleavage of .alpha.-nitrogen-hydrogen bonds in carboxamides, sulfonamides, and their derivatives. The question of synergism in nitrogen-centered radicals

作者： F. G. Bordwell , J. A. Harrelson , Tsuei Yun Lynch

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摘要: Estimates of homolytic bond dissociation energies (BDEs) the N-H bonds acetamide, benzamide, and benzenesulfonamide by measurements their equilibrium acidities oxidation potentials conjugate bases in dimethyl sulfoxide (DMSO) solution place them within experimental error that ammonia (107 kcal/mol)

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Homolytic bond dissociation energies for the cleavage of .alpha.-nitrogen-hydrogen bonds in carboxamides, sulfonamides, and their derivatives. The question of synergism in nitrogen-centered radicals

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Homolytic bond dissociation energies for the cleavage of .alpha.-nitrogen-hydrogen bonds in carboxamides, sulfonamides, and their derivatives. The question of synergism in nitrogen-centered radicals

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