Recent advances in the syntheses of homopolyatomic cations of the non metallic elements C, N, P, S, Cl, Br, I and Xe

作者: Tobias A. Engesser , Ingo Krossing

DOI: 10.1016/J.CCR.2012.07.025

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摘要: Abstract The electronegative non metallic elements have high electron affinities and ionization potentials thus a strong tendency to form anions. To work against the naturally negative charge of non-metals, inspired continues inspire chemists around world. Nevertheless, it still is one tough challenges in inorganic chemistry selectively synthesize pure homopolyatomic cations metals. Over last hundred years characterization most those were described literature. Even very recent brought new exciting examples, e.g. N, P, Sb others. Herein advances towards syntheses over fifteen are reviewed.

参考文章(134)
Tobias Köchner, Tobias A. Engesser, Harald Scherer, Dietmar A. Plattner, Alberto Steffani, Ingo Krossing, [P9]+[Al(ORF)4]−, the Salt of a Homopolyatomic Phosphorus Cation Angewandte Chemie. ,vol. 51, pp. 6529- 6531 ,(2012) , 10.1002/ANIE.201201262
Claude R. Lassigne, E. J. Wells, Identification of the species [TenSe4–n]2+ by high resolution 125Te and 123Te Fourier transform n.m.r. spectroscopy Journal of The Chemical Society, Chemical Communications. pp. 956- 957 ,(1978) , 10.1039/C39780000956
R. O. Jones, D. Hohl, Structure of phosphorus clusters using simulated annealing—P2 to P8 Journal of Chemical Physics. ,vol. 92, pp. 6710- 6721 ,(1990) , 10.1063/1.458306
R. J. Gillespie, J. Passmore, The compounds S8(AsF6)2 and S16(AsF6)2 Journal of the Chemical Society D: Chemical Communications. pp. 1333- 1334 ,(1969) , 10.1039/C29690001333
N.J. Bjerrum, C.R. Boston, G.P. Smith, H.L. Davis, Unusual oxidation states of bismuth produced by the reaction between bismuth metal and Bi(III) in acid chloride media Inorganic and Nuclear Chemistry Letters. ,vol. 1, pp. 141- 143 ,(1965) , 10.1016/S0020-1650(65)80022-8
D. Michael P. Mingos, Polyhedral skeletal electron pair approach Accounts of Chemical Research. ,vol. 17, pp. 311- 319 ,(1984) , 10.1021/AR00105A003
Alexei N. Kuznetsov, Boris A. Popovkin, Kenny Ståhl, Martin Lindsjö, Lars Kloo, Synthesis of Main Group Polycations in Molten and Pseudo‐Molten GaBr3 Media European Journal of Inorganic Chemistry. ,vol. 2005, pp. 4907- 4913 ,(2005) , 10.1002/EJIC.200500161
Gary J. Schrobilgen, Robert C. Burns, Pierre Granger, 125-Tellurium and 77-selenium multinuclear magnetic resonance studies of Te64+, Te4–nSen2+, Te2Se42+, and Te3Se32+ polyatomic cations Journal of The Chemical Society, Chemical Communications. pp. 957- 960 ,(1978) , 10.1039/C39780000957
Jack Passmore, George Sutherland, Peter S. White, Preparation and crystal structures of (S7I)4S4(AsF6)6 and S4(AsF6)2·0.6SO2; a convenient synthesis of hexafluoroarsenate salts of chalcogen homoatomic cations Journal of The Chemical Society, Chemical Communications. pp. 330- 331 ,(1980) , 10.1039/C39800000330