Well-defined nickel and palladium precatalysts for cross-coupling
作者： Nilay Hazari , Patrick R. Melvin , Megan Mohadjer Beromi
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摘要: Transition metal-catalysed cross-coupling is one of the most powerful synthetic methods and has led to vast improvements in the synthesis of pharmaceuticals, agrochemicals and precursors for materials chemistry. A major advance in cross-coupling over the past 20 years is the utilization of well-defined, bench-stable Pd and Ni precatalysts that do not require the addition of free ancillary ligand, which can hinder catalysis by occupying open coordination sites on the metal. The development of precatalysts has resulted in new reactions and …
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Lensey L Hill, Jason L Crowell, Strudwick L Tutwiler, Nicholas L Massie, C Corey Hines, Scott T Griffin, Robin D Rogers, Kevin H Shaughnessy, Gabriela A Grasa, Carin CC Johansson Seechurn, Hongbo Li, Thomas J Colacot, Joe Chou, Christopher J Woltermann, None, Synthesis and X-ray Structure Determination of Highly Active Pd(II), Pd(I), and Pd(0) Complexes of Di(tert-butyl)neopentylphosphine (DTBNpP) in the Arylation of Amines and Ketones Journal of Organic Chemistry. ,vol. 75, pp. 6477- 6488 ,(2010) , 10.1021/JO101187Q
Nicholas D. Staudaher, Ryan M. Stolley, Janis Louie, Synthesis, mechanism of formation, and catalytic activity of Xantphos nickel π-complexes Chemical Communications. ,vol. 50, pp. 15577- 15580 ,(2014) , 10.1039/C4CC07590K
Xin-Heng Fan, Lian-Ming Yang, NiII-(σ-Aryl) Complex Catalyzed Suzuki Reaction of Aryl Tosylates with Arylboronic Acids European Journal of Organic Chemistry. ,vol. 2010, pp. 2457- 2460 ,(2010) , 10.1002/EJOC.201000147
Aurora Antoft-Finch, Tom Blackburn, Victor Snieckus, N,N-Diethyl O-Carbamate: Directed Metalation Group and Orthogonal Suzuki−Miyaura Cross-Coupling Partner Journal of the American Chemical Society. ,vol. 131, pp. 17750- 17752 ,(2009) , 10.1021/JA907700E
José A. Fernández-Salas, Enrico Marelli, David B. Cordes, Alexandra M. Z. Slawin, Steven P. Nolan, General and mild Ni0-catalyzed α-arylation of ketones using aryl chlorides Chemistry: A European Journal. ,vol. 21, pp. 3906- 3909 ,(2015) , 10.1002/CHEM.201406457
Yusuke Makida, Enrico Marelli, Alexandra M. Z. Slawin, Steven P. Nolan, Nickel-catalysed carboxylation of organoboronates. Chemical Communications. ,vol. 50, pp. 8010- 8013 ,(2014) , 10.1039/C4CC03650F
Sebastian Würtz, Frank Glorius, Surveying sterically demanding N-heterocyclic carbene ligands with restricted flexibility for palladium-catalyzed cross-coupling reactions. Accounts of Chemical Research. ,vol. 41, pp. 1523- 1533 ,(2008) , 10.1021/AR8000876
Javier Magano, Joshua R. Dunetz, Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals. Chemical Reviews. ,vol. 111, pp. 2177- 2250 ,(2011) , 10.1021/CR100346G
Virgil Percec, Jin-Young Bae, Dale H. Hill, Aryl Mesylates in Metal Catalyzed Homocoupling and Cross-Coupling Reactions. 2. Suzuki-Type Nickel-Catalyzed Cross-Coupling of Aryl Arenesulfonates and Aryl Mesylates with Arylboronic Acids Journal of Organic Chemistry. ,vol. 60, pp. 1060- 1065 ,(1995) , 10.1021/JO00109A044
David S. McGuinness, Kingsley J. Cavell, Brian W. Skelton, Allan H. White, Zerovalent palladium and nickel complexes of heterocyclic carbenes: Oxidative addition of organic halides, carbon-carbon coupling processes, and the Heck reaction Organometallics. ,vol. 18, pp. 1596- 1605 ,(1999) , 10.1021/OM9809771