Modeling the catalytic process of cyclohexane isomerization to methylcyclopentane
作者： E. V. Pisarenko , V. N. Pisarenko , A. B. Ponomarev
DOI: 10.1134/S0040579517020063
关键词:
摘要: The kinetics of the isomerization cyclohexane to methylcyclopentane on Pd-mordenite catalyst in a flow reactor has been studied. In experiments, parameters such as volumetric rate feedstock, component composition feed gas (cyclohexane, methylcyclopentane, hydrogen), and temperature pressure have varied. concentrations hydrogen, cyclohexane, determined. A stepwise reaction mechanism suggested. kinetic model that contains direct constant limiting stage combination equilibrium constants fast stages set for estimating built. An additional precision (improving) experiment shown are estimated with high accuracy. predictive ability under experimental conditions proved be high.
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