Practical Preparation of 2-Halomethyl-Allyl Carboxylates

作者: Chong-Si Sun , Hsiu-Yi Cheng , Yu-Shiang Lin , Duen-Ren Hou

DOI: 10.1002/JCCS.200800065

关键词:

摘要: An improved, efficient preparation of 2-(halomethyl)allyl carboxylates starting from diethyl bis(hydroxymethyl)malonate and hydrobromic acid is reported. The allylic halogen 2-(chloromethyl)acrylate 2-(bromomethyl)acrylate are readily exchanged during esterification.

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