Surface modification of silica-coated gadolinium oxide nanoparticles with zinc tetracarboxyphenoxy phthalocyanine for the photodegradation of Orange G

作者: Mpho Ledwaba , Nkosiphile Masilela , Tebello Nyokong , Edith Antunes

DOI: 10.1016/J.MOLCATA.2015.03.023

关键词:

摘要: Abstract Zinc tetracarboxyphenoxy phthalocyanine was covalently linked to Gd 2 O 3 nanoparticles for the photocatalytic degradation of Orange G. Characterization composite carried out using XRD, TEM, XPS, UV–vis spectroscopy and FT-IR spectroscopy. The showed improved photophysical properties over alone catalyst found be reusable. Analyses photodegradation rates azo dye indicated pseudo first-order kinetics.

参考文章(47)
Chris D. Geddes, Joseph R. Lakowicz, Editorial Metal-Enhanced Fluorescence Journal of Fluorescence. ,vol. 12, pp. 121- 129 ,(2002) , 10.1023/A:1016875709579
Foil A. Miller, R. W. Hannah, Dana W. Mayo, Course Notes on the Interpretation of Infrared and Raman Spectra ,(2004)
Andrew Gilbert, J. E. Baggott, Essentials of Molecular Photochemistry ,(1991)
Nicholas J. Turro, Modern Molecular Photochemistry ,(1978)
T. H. Tran Thi, C. Desforge, C. Thiec, S. Gaspard, Singlet−singlet and triplet−triplet intramolecular transfer processes in a covalently linked porphyrin−phthalocyanine heterodimer The Journal of Physical Chemistry. ,vol. 93, pp. 1226- 1233 ,(1989) , 10.1021/J100341A013
Suzanne Fery-Forgues, Dominique Lavabre, ARE FLUORESCENCE QUANTUM YIELDS SO TRICKY TO MEASURE? A DEMONSTRATION USING FAMILIAR STATIONERY PRODUCTS Journal of Chemical Education. ,vol. 76, pp. 1260- 1264 ,(1999) , 10.1021/ED076P1260
R. Bazzi, M.A. Flores-Gonzalez, C. Louis, K. Lebbou, C. Dujardin, A. Brenier, W. Zhang, O. Tillement, E. Bernstein, P. Perriat, Synthesis and luminescent properties of sub-5-nm lanthanide oxides nanoparticles Journal of Luminescence. ,vol. 102, pp. 445- 450 ,(2003) , 10.1016/S0022-2313(02)00588-4
Somsakul Watcharinyanon, Daniel Nilsson, Ellen Moons, Andrey Shaporenko, Michael Zharnikov, Bo Albinsson, Jerker Mårtensson, Lars S. O. Johansson, A spectroscopic study of self-assembled monolayer of porphyrin-functionalized oligo(phenyleneethynylene)s on gold: the influence of the anchor moiety. Physical Chemistry Chemical Physics. ,vol. 10, pp. 5264- 5275 ,(2008) , 10.1039/B802914H
Mark O. Liu, Chia-Hon Tai, Andrew Teh Hu, Tai-Huei Wei, Reverse saturable absorption of lanthanide bisphthalocyanines and their application for optical switches Journal of Organometallic Chemistry. ,vol. 689, pp. 2138- 2143 ,(2004) , 10.1016/J.JORGANCHEM.2004.04.003