ACTINIDE PARTITIONING—A REVIEW
作者： J. N. Mathur , M. S. Murali , K. L. Nash
关键词:
摘要: Reagents and methods that have been developed during the past 20 years for hydrometallurgical partitioning of actinides from different types transuranium (TRU) wastes dissolved fuels are reviewed. Emphasis is placed on extraction performance fully-optimized reagents rather than structural iterations were undertaken (and in some cases still being conducted) to identify optimum species. Particular attention paid separation processes demonstrated batch counter-current solvent extraction, column mode chromatography. The salient features various techniques actinide recycle compared. Sections review focus neptunium behavior hydrometallurgy characterization those best suited trivalent fission product lanthanides. Selected flowsheets reported recovery TRU presented.
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sci-hub.se 参考文章(98)
C. Cuillerdier, C. Musikas, P. Hoel, TREATMENT OF NUCLEAR WASTE SOLUTIONS USING A NEW CLASS OF EXTRACTANTS: PENTAALKYL PROPANE DIAMIDES Springer, Dordrecht. pp. 41- 48 ,(1991) , 10.1007/978-94-011-3654-9_8
Kenneth L. Nash, Chapter 121 Separation chemistry for lanthanides and trivalent actinides Lanthanides/Actinides: Chemistry. ,vol. 18, pp. 197- 238 ,(1994) , 10.1016/S0168-1273(05)80044-3
L.L. Martella, J.D. Navratil, Waste management analysis for the nuclear fuel cycle. I. Actinide recovery from aqueous salt wastes ,(1979) , 10.2172/6221971
T.H. Siddall, Bidentate organophosphorus compounds as extractants—II Journal of Inorganic and Nuclear Chemistry. ,vol. 26, pp. 1991- 2003 ,(1964) , 10.1016/0022-1902(64)80024-5
James D. Navratil, Gary H. Thompson, Removal of actinides from selected nuclear fuel reprocessing wastes Nuclear Technology. ,vol. 43, pp. 136- 145 ,(1979) , 10.13182/NT79-A16305
E. PHILIP HORWITZ, HERBERT DIAMOND, DALE G. KALINA, Carbamoylmethylphosphoryl derivatives as actinide extractants: their significance in the processing and recovery of plutonium and other actinides ACS Symp. Ser.; (United States). ,vol. 216, ,(1983) , 10.1021/BK-1983-0216.CH027
Brian M. Rapko, Synthesis, Characterization and Actinide Extraction Behavior of Bridge-Modified Carbamoylmethyl Phosphonates and Phosphine Oxides Springer, Boston, MA. pp. 99- 123 ,(1995) , 10.1007/978-1-4899-1406-4_8
R.G. Cowan, G.S. Barney, Separation of actinide ions from radioactive waste solutions using extraction chromatography ,(1992)
G.J. Lumetta, J.L. Swanson, Pretreatment of neutralized cladding removal waste (NCRW) sludge: Results of FY 1991 studies ,(1993) , 10.2172/6863273
J. N. Mathur, M. S. Murali, R. H. Iyer, A. Ramanujam, P. S. Dhami, V. Gopalakrishnan, M. K. Rao, L. P. Badheka, Asoke Banerji, Extraction chromatographic separation of minor actinides from purex high-level wastes using CMPO Nuclear Technology. ,vol. 109, pp. 216- 225 ,(1995) , 10.13182/NT95-A35054