RRDE study of oxygen reduction on Pt nanoparticles inside Nafion®: H2O2 production in PEMFC cathode conditions

作者: O. Antoine , R. Durand

DOI: 10.1023/A:1003999818560

关键词:

摘要: … As on bulk platinum, a four-electron mechanism appears to be the main pathway, with particle size and carbon substrate effects on the H2O2 production. A large increase in the H2O2 …

参考文章(22)
K.-L. Hsueh, D.-T. Chin, S. Srinivasan, Electrode kinetics of oxygen reduction: A theoretical and experimental analysis of the rotating ring-disc electrode method Journal of Electroanalytical Chemistry. ,vol. 153, pp. 79- 95 ,(1983) , 10.1016/S0022-0728(83)80007-2
A. Kabbabi, F. Gloaguen, F. Andolfatto, R. Durand, Particle size effect for oxygen reduction and methanol oxidation on Pt/C inside a proton exchange membrane Journal of Electroanalytical Chemistry. ,vol. 373, pp. 251- 254 ,(1994) , 10.1016/0022-0728(94)03503-2
Evelyn K.W. Lai, Paul D. Beattie, Francesco P. Orfino, Evelyne Simon, Steven Holdcroft, Electrochemical oxygen reduction at composite films of Nafion®, polyaniline and Pt Electrochimica Acta. ,vol. 44, pp. 2559- 2569 ,(1999) , 10.1016/S0013-4686(98)00389-2
C.F. Zinola, A.M. Castro Luna, W.E. Triaca, A.J. Arvia, Electroreduction of molecular oxygen on preferentially oriented platinum electrodes in acid solution Journal of Applied Electrochemistry. ,vol. 24, pp. 119- 125 ,(1994) , 10.1007/BF00247782
G. Kokkinidis, D. Jannakoudakis, Oxygen reduction on Pt and Cu surfaces modified by underpotential adsorbates Journal of Electroanalytical Chemistry. ,vol. 162, pp. 163- 173 ,(1984) , 10.1016/S0022-0728(84)80162-X
A. Damjanovic, M. A. Genshaw, J. O'M. Bockris, Distinction between Intermediates Produced in Main and Side Electrodic Reactions Journal of Chemical Physics. ,vol. 45, pp. 4057- 4059 ,(1966) , 10.1063/1.1727457
V. Vesovic, N. Anastasijevic, R.R. Adzic, Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction Journal of Electroanalytical Chemistry. ,vol. 218, pp. 53- 63 ,(1987) , 10.1016/0022-0728(87)87005-5
FV Hanson, M Boudart, The reaction between H2 and O2 over supported platinum catalysts Journal of Catalysis. ,vol. 53, pp. 56- 67 ,(1978) , 10.1016/0021-9517(78)90007-6