Electronic spectra and structure of the hydrogen halides the b 3Πi and C 1Π states of HI and DI
作者： S.G Tilford , M.L Ginter , Arnold M Bass
DOI: 10.1016/0022-2852(70)90098-6
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摘要: Abstract The absorption spectra of HI and DI below 1900 A have been photographed at high resolution. Analyses the “B” ← X C transitions show that state is 3Πi component a (designated here as b) 1Π state. Both b 3 Π i 1 originate from same π3σ configuration, exhibit strong predissociations, some small Case c effects. transition approximately Λ, S toward Ω , ω coupling discussed for states hydrogen halides, HCl, DCl, HBr, DBr, HI, DI. Effective molecular constants are presented
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