Selectivity Control in Nickel-Catalyzed Olefin Oligomerization
作者： B. Bogdanovlć
DOI: 10.1016/S0065-3055(08)60322-6
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摘要: Publisher Summary The chapter explains the material concerning control of selectivity in nickel-catalyzed homogeneous oligomerization olefins and related reactions. is also concerned with problems usually encountered olefin product catalytic dimerization a single olefin, such as ethylene, general mixture dimers lesser amounts higher oligomers. It frequently possible to vs. oligomerization—that is, percentage product. problem particularly important two different when, addition required co-dimers, homo-dimers may be produced. A challenging situation catalysis particular that stereo-selectivity control, including dia-stereoselectivity enantio-selectivity. Reactions leading formation catalytically active nickel hydride species from organonickel precursors can regarded model reactions for various examples (a) course reactions, (b) (c) isomerization, (d) involving 1, 5- 6-dienes, (e) propene, (f) enantio-selectivity are discussed this chapter.
sci-hub.se 参考文章(41)
Gisela Henrici-Olivé, Salvador Olivé, Olefin insertion in transition metal catalysis ChemInform. ,vol. 8, pp. 107- 127 ,(1976) , 10.1007/BFB0048499
Gisela Henrici-Oliv�, Salvador Oliv�, Reactions of carbon monoxide with transition metal-carbon bonds Transition Metal Chemistry. ,vol. 1, pp. 77- 93 ,(1976) , 10.1007/BF01385947
G. Lefebvre, Y. Chauvin, Dimerization and Co-dimerization of Olefinic Compounds by Co-ordination Catalysis Springer, Dordrecht. pp. 107- 201 ,(1970) , 10.1007/978-94-010-3341-1_3
S. Olivé, G. Henrici-Olivé, Coordination and catalysis ,(1976)
G. Wilke, Peter W. Jolly, The organic chemistry of nickel ,(1974)
Eiichi HAYASHI, Susumu NARUI, Masanori OTA, Mutsuji SAKAI, Yasumasa SAKAKIBARA, Norito UCHINO, ニッケルアセチルアセトナート-トリエチルアルミニウムセスキクロリド-トリフェニルホスフィン触媒によるプロピレンの二量化反応 Nippon Kagaku Kaishi. ,vol. 74, pp. 1834- 1838 ,(1971) , 10.1246/NIKKASHI1898.74.9_1834
L. Porri, G. Natta, M. C. Gallazzi, Stereospecific polymerization of butadiene by catalysts prepared from π‐allyl nickel halides Journal of Polymer Science Part C: Polymer Symposia. ,vol. 16, pp. 2525- 2537 ,(1967) , 10.1002/POLC.5070160507
Melvyn R. Churchill, Thomas A. O'Brien, The crystal and molecular structure of dimeric 2-carboxyethyl-p-allylnickel bromide Inorganic Chemistry. ,vol. 6, pp. 1386- 1390 ,(1967) , 10.1021/IC50053A022
J. R. Jones, T. J. Symes, Linear dimerisation of 1-olefins catalysed by complexes of nickel β-diketonates and aluminium alkyls J. Chem. Soc. C. ,vol. 0, pp. 1124- 1130 ,(1971) , 10.1039/J39710001124
R DEHAAN, Catalytic dimerization of propylene: II. Nickel tetracarbonyl as zerovalent nickel catalyst Journal of Catalysis. ,vol. 44, pp. 15- 24 ,(1976) , 10.1016/0021-9517(76)90370-5