Complete and Partial Electron Transfer Involving Coordinated NOx
作者： Wolfgang Kaim
DOI: 10.1016/BS.ADIOCH.2014.10.007
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摘要: Abstract The role of metal coordination in the stabilization various oxidation states NOx (x = +,0,−,2 −) and its relation to N2O NO2 is discussed by example transition complexes. In addition structural information from experiments calculations, results spectroscopic studies (IR, EPR) connection with electrochemistry provide evidence for appropriate state description associated reactivity, revealing a continuum charge parameter x.
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