Configurational effects of templating on the adsorption isotherms of templated porous materials
作者： LINGHUI ZHANG , PAUL R. VAN TASSEL
DOI: 10.1080/00268970009483357
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摘要: The porosity and pore geometry of disordered materials can be influenced by employing a removable template during synthesis. A theoretical simulation study is reported the configurational effects size density on adsorption isotherms templated porous materials. To isolate (entropic) contributions, adsorbate, matrix components are modelled as hard spheres. replica Ornstein-Zernike equations proposed Zhang, L. Van Tassel, P. R. (2000) J. chem Phys., 112, 3006 used within Percus-Yevick approximation to calculate for differently sized adsorbate components. These results compared with from Monte Carlo simulation. It found that most enhanced whenever equal or slightly larger than adsorbate. Also, systems constant plus density, increasing e...
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