摘要: The mechanism of formation electronically excited species in elementary gas reactions is discussed some detail. It shown that three-body recombination normally a more efficient source molecules than two-body association. atom transfer considered terms the potential surfaces involved and their intersections. A brief comparison made with mechanisms chemiluminescence organic biological systems.
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Kurt E. Shuler, Adiabatic Correlation Rules for Reactions Involving Polyatomic Intermediate Complexes and their Application to the Formation of OH(2Σ+) in the H2–O2 Flame The Journal of Chemical Physics. ,vol. 21, pp. 624- 632 ,(1953) , 10.1063/1.1698979
J. W. T. Spinks, Gerhard Herzberg, Spectra of diatomic molecules Van Nostrand Reinhold. ,(1950)
M. C. Moulton, D. R. Herschbach, Chemiluminescence in Molecular Beams. Electronic Excitation of Alkali Atoms in Exchange Reactions of Vibrationally Excited Alkali Halides Journal of Chemical Physics. ,vol. 44, pp. 3010- 3018 ,(1966) , 10.1063/1.1727171
Howard B. Palmer, Ralph A. Carabetta, Radiative Recombination of Chlorine Atoms in Shock Waves: A Re‐examination The Journal of Chemical Physics. ,vol. 49, pp. 2466- 2468 ,(1968) , 10.1063/1.1670438
Rolf W. F. Gross, Norman Cohen, Temperature Dependence of Chemiluminescent Reactions. II. Nitric Oxide Afterglow Journal of Chemical Physics. ,vol. 48, pp. 2582- 2588 ,(1968) , 10.1063/1.1669486
L. F. Phillips, T. M. Sugden, Some rate-constants for termolecular excitation reactions of atoms in flames Transactions of the Faraday Society. ,vol. 57, pp. 2188- 2196 ,(1961) , 10.1039/TF9615702188
M. A. A. Clyne, J. A. Coxon, A. R. Woon Fat, Recombination of ground state halogen atoms. Part 3.—Radiative Recombination of Br2PAtoms Faraday Discuss. Chem. Soc.. ,vol. 53, pp. 82- 99 ,(1972) , 10.1039/DC9725300082
Roald Hoffmann, The Conservation of Orbital Symmetry Angewandte Chemie International Edition in English. ,vol. 8, pp. 781- 853 ,(1969) , 10.1002/ANIE.196907811
David R. Kearns, Selection rules for singlet-oxygen reactions. Concerted addition reactions Journal of the American Chemical Society. ,vol. 91, pp. 6554- 6563 ,(1969) , 10.1021/JA01052A003
Michael Mandelman, Tucker Carrington, Robert A. Young, Predissociation and its inverse, using resonance absorption NO(C 2Π) ⇄ N+O The Journal of Chemical Physics. ,vol. 58, pp. 84- 90 ,(1973) , 10.1063/1.1678956