Structural study of glasses in the system B 2 O 3 -Bi 2 O 3 -La 2 O 3 -WO 3
作者： Reni Iordanova , Margarita Milanova , Lyubomir Aleksandrov , Atul Khanna
DOI: 10.1016/J.JNONCRYSOL.2017.10.041
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摘要: Abstract New multicomponent (100 − (x − y))·(0.6B2O3·0.4Bi2O3)·xLa2O3·yWO3, x = 0, 10; y = 0 ÷ 40 mol% glasses were obtained by melt quenching technique and its structure examined infrared Raman spectroscopies. Based on the spectral data it was suggested that in absence of La2O3, tungsten incorporates into boro-bismuthate network small quantities through Bi3 + В О W bonds are not formed. Accumulation Bi O stimulates crystallization processes. La2O3 is crucial to connect tungstate units with boro‑bismuthate glass matrix realize amorphous their participation. It supposed higher WO3 content (30 40 mol%) two inconsisted networks formed bismuth-borate one built up BO3, BO4, BiO6 one, mainly WO6. These interconnected lanthanum.
sci-hub.se 参考文章(66)
R. Tong, Z. Wang, D. Yang, H. Lin, Influence of WO3 content on the optical properties of Eu3+-doped Bi2O3-B2O3-WO3 glasses Materials Science-poland. ,(2009)
R.G. Gossink, Properties of vitreous and molten alkali molybdates and tungstates Technische Hogeschool Eindhoven. ,(1971)
Raouf A.H. El-Mallawany, Tellurite Glasses Handbook: Physical Properties and Data ,(2014)
Petru Pascuta, Lidia Pop, Simona Rada, Maria Bosca, Eugen Culea, The local structure of bismuth borate glasses doped with europium ions evidenced by FT-IR spectroscopy Journal of Materials Science: Materials in Electronics. ,vol. 19, pp. 424- 428 ,(2008) , 10.1007/S10854-007-9359-5
Atul Khanna, K J S Sawhney, M K Tiwari, Suresh Bhardwaj, A M Awasthi, Effects of melt ageing on the density, elastic modulus and glass transition temperature of bismuth borate glasses Journal of Physics: Condensed Matter. ,vol. 15, pp. 6659- 6670 ,(2003) , 10.1088/0953-8984/15/40/004
M. Milanova, R. Iordanova, L. Aleksandrov, M. Hassan, Y. Dimitriev, Glass formation and structure of glasses in the ZnO―Bi2O3―WO3―MoO3 system Journal of Non-crystalline Solids. ,vol. 357, pp. 2713- 2718 ,(2011) , 10.1016/J.JNONCRYSOL.2011.03.015
Yin Cheng, Hanning Xiao, Wenming Guo, Weiming Guo, Structure and crystallization kinetics of Bi2O3-B2O3 glasses Thermochimica Acta. ,vol. 444, pp. 173- 178 ,(2006) , 10.1016/J.TCA.2006.03.016
Regis J. Betsch, William B. White, Vibrational spectra of bismuth oxide and the sillenite-structure bismuth oxide derivatives Spectrochimica Acta Part A: Molecular Spectroscopy. ,vol. 34, pp. 505- 514 ,(1978) , 10.1016/0584-8539(78)80047-6
M. Mączka, V. Nikolov, K. Hermanowicz, A. Yordanova, M. Kurnatowska, J. Hanuza, Optical and phonon properties of nanocrystalline Al2(WO4)3 doped with chromium(III) prepared by co-precipitation method Optical Materials. ,vol. 34, pp. 1048- 1053 ,(2012) , 10.1016/J.OPTMAT.2011.12.016
Stuart D. Jackson, Continuous wave 2.9 μm dysprosium-doped fluoride fiber laser Applied Physics Letters. ,vol. 83, pp. 1316- 1318 ,(2003) , 10.1063/1.1603353