Synthesis, structure, and reactivity of homoleptic tin(II) and lead(II) chalcogenolates and conversion to metal chalcogenides. X-ray crystal structures of {Sn[TeSi(SiMe3)3]2}2 and (PMe3)Sn[TeSi(SiMe3)3]2
作者： Allen L. Seligson , John Arnold
DOI: 10.1021/JA00071A034
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摘要: The preparation and characterization of homoleptic tin(II) lead(II) tellurolates, selenolates, thiolates incorporating bulky ESi(SiMe 3 ) ligands (E=Te, Se, S) are described. derivatives M[ESi(SiMe ] 2 (M=Sn:1, E=Te; 3, E=Se; 5, E=S. M=Pb: 2, 4, 6, E=S) prepared via protonolysis M [N(SiMe with HESi(SiMe
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