Heterogeneous photocatalytic degradation of 4-nitrophenol in aqueous suspension by Ln (La3+, Nd3+ or Sm3+) doped ZnO nanoparticles

作者: M. Khatamian , A.A. Khandar , B. Divband , M. Haghighi , S. Ebrahimiasl

DOI: 10.1016/J.MOLCATA.2012.08.018

关键词:

摘要: Lanthanide doped ZnO nanoparticles with different Ln (Ln= La, Nd and Sm) contents were synthesized by polymer pyrolysis method and characterized by various techniques such as XRD, UV–vis, SEM, TGA, and TEM. The XRD results revealed that Ln3+ is uniformly dispersed on ZnO nanoparticles in the form of small Ln2O3 cluster. From SEM and TEM images it was found that the particle size of La-doped ZnO is much smaller as compared to that of pure ZnO. The photocatalytic activity of La-doped ZnO in the degradation of 4 …

参考文章(35)
Srinivasan Anandan, Ajayan Vinu, Toshiyuki Mori, Narasimhan Gokulakrishnan, Pavuluri Srinivasu, Velayutham Murugesan, Katsuhiko Ariga, None, Photocatalytic Degradation of 2,4,6-Trichlorophenol Using Lanthanum Doped ZnO in Aqueous Suspension Catalysis Communications. ,vol. 8, pp. 1377- 1382 ,(2007) , 10.1016/J.CATCOM.2006.12.001
Gao-Ren Li, Xi-Hong Lu, Cheng-Yong Su, Ye-Xiang Tong, Facile Synthesis of Hierarchical ZnO:Tb3+ Nanorod Bundles and Their Optical and Magnetic Properties Journal of Physical Chemistry C. ,vol. 112, pp. 2927- 2933 ,(2008) , 10.1021/JP710519Q
XM Teng, HT Fan, SS Pan, C Ye, GH Li, None, Influence of annealing on the structural and optical properties of ZnO:Tb thin films Journal of Applied Physics. ,vol. 100, pp. 053507- ,(2006) , 10.1063/1.2227268
S Anandan, A Vinu, KLP Sheeja Lovely, N Gokulakrishnan, P Srinivasu, T Mori, V Murugesan, V Sivamurugan, K Ariga, None, Photocatalytic activity of La-doped ZnO for the degradation of monocrotophos in aqueous suspension Journal of Molecular Catalysis A-chemical. ,vol. 266, pp. 149- 157 ,(2007) , 10.1016/J.MOLCATA.2006.11.008
Lidia Armelao, Gregorio Bottaro, Michele Pascolini, Michele Sessolo, Eugenio Tondello, Marco Bettinelli, Adolfo Speghini, Structure−Luminescence Correlations in Europium-Doped Sol−Gel ZnO Nanopowders Journal of Physical Chemistry C. ,vol. 112, pp. 4049- 4054 ,(2008) , 10.1021/JP710207R
V. Bhosle, A. Tiwari, J. Narayan, Electrical properties of transparent and conducting Ga doped ZnO Journal of Applied Physics. ,vol. 100, pp. 033713- ,(2006) , 10.1063/1.2218466
A.S. Pereira, M.A. Martins, T. Trindade, E. Alves, S.S. Nobre, R.A. Sá Ferreira, M. Peres, A. Cruz, S. Pereira, M.R. Correia, M.J. Soares, A. Neves, M.C. Carmo, T. Monteiro, Optical studies of ZnO nanocrystals doped with Eu3+ ions Applied Physics A. ,vol. 88, pp. 129- 133 ,(2007) , 10.1007/S00339-007-3941-9
Gao-Ren Li, Ci-Ren Dawa, Xi-Hong Lu, Xiao-Lan Yu, Ye-Xiang Tong, Use of additives in the electrodeposition of nanostructured Eu3+/ZnO films for photoluminescent devices. Langmuir. ,vol. 25, pp. 2378- 2384 ,(2009) , 10.1021/LA801601G
Xian-Ming Liu, Guo Yang, Shao-Yun Fu, Mass synthesis of nanocrystalline spinel ferrites by a polymer-pyrolysis route Materials Science and Engineering: C. ,vol. 27, pp. 750- 755 ,(2007) , 10.1016/J.MSEC.2006.07.026
Xiaoyan Zeng, Junlin Yuan, Lide Zhang, Synthesis and Photoluminescent Properties of Rare Earth Doped ZnO Hierarchical Microspheres Journal of Physical Chemistry C. ,vol. 112, pp. 3503- 3508 ,(2008) , 10.1021/JP0768118