ELECTROCHEMICAL AND ELECTRIC-FIELD EFFECTS AT DISPERSIONS OF ZEOLITES

作者: Debra R. ROLISON , Joseph Z. STEMPLE , David J. CURRAN

DOI: 10.1016/B978-1-4832-8383-8.50168-9

关键词:

摘要: Application of dc voltages (< 100 V) to aqueous dispersions native zeolites and modified with known molecular catalysts permits chemical reactivities either not observed in the absence electrifying force or at much slower rates. Although are routinely used for aqueous-phase catalysis, use electric fields potentials applied zeolite suspensions affects rate exchange alkali ion phase protons generated by autoprotolysis water. The kinetics this process depend on nature charge-compensating cation magnitude field.

参考文章(9)
J. Ghoroghchian, S. Pons, M. Fleischmann, Gas phase electrochemistry on dispersions of microelectrodes Journal of Electroanalytical Chemistry. ,vol. 317, pp. 101- 108 ,(1991) , 10.1016/0022-0728(91)85005-A
Martin Fleischmann, Jamal Ghoroghchian, Debra Rolison, Stanley Pons, Electrochemical behavior of dispersions of spherical ultramicroelectrodes The Journal of Physical Chemistry. ,vol. 90, pp. 6392- 6400 ,(1986) , 10.1021/J100281A065
Debra R. Rolison, Robert J. Nowak, Timothy A. Welsh, Catherine G. Murray, Analytical implications of zeolites in overlayers at electrodes. Talanta. ,vol. 38, pp. 27- 35 ,(1991) , 10.1016/0039-9140(91)80006-L
Pierre Gallezot, The State and Catalytic Properties of Platinum and Palladium in Faujasite-type Zeolites Catalysis Reviews-science and Engineering. ,vol. 11, pp. 121- 154 ,(1979) , 10.1080/03602457908065108
Debra R. Rolison, Zeolite-modified electrodes and electrode-modified zeolites Chemical Reviews. ,vol. 90, pp. 867- 878 ,(1990) , 10.1021/CR00103A011
A. S. Buchanan, S. D. James, Electrochemistry of the Interface between Some Aluminosilicate Crystals and Salt Solutions. II. Electrokinetic Charge The Journal of Physical Chemistry. ,vol. 70, pp. 3454- 3458 ,(1966) , 10.1021/J100883A014
Debra R. Rolison, E. A. Hayes, W. E. Rudzinski, Electrode-modified zeolites: electrode microstructures contained in and on a heterogeneous catalyst The Journal of Physical Chemistry. ,vol. 93, pp. 5524- 5531 ,(1989) , 10.1021/J100351A040