Analytical solution of vibrational–rotational energy transfer in the dissociation and relaxation of N2, Br2, and CO at high temperature
作者： Wendell Forst
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摘要: An approximate analytical solution of relaxation in a low-pressure system with exponential transition probabilities is given for vibrational–rotational energy transfer the dissociation diatomics. The main assumption that rotational degrees freedom are thermal equilibrium at all times, and barrier to plane linear asymmetric. theory applied high-temperature dissociations N2, Br2, CO excess argon, satisfactory agreement available experimental data.
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