Biosorption of chromium by alginate extraction products from Sargassum filipendula: investigation of adsorption mechanisms using X-ray photoelectron spectroscopy analysis.

作者: Caroline Bertagnolli , Arnaud Uhart , Jean-Charles Dupin , Meuris Gurgel Carlos Da Silva , Eric Guibal

DOI: 10.1016/J.BIORTECH.2014.04.103

关键词:

摘要: The alginate extraction products from Brazilian brown seaweed Sargassum filipendula were studied for chromium biosorption. Batch experiments conducted at pH 2 and 3 20°C to determine the sorption capacity of this biosorbents (VI) (III). biomass was characterized before after metal binding by X-ray photoelectron spectroscopy (XPS) in order mechanisms residue has a high adsorption capacity, close value obtained with higher than that both Cr(III) Cr(VI). XPS analysis revealed carboxyl, amino sulfonate groups are responsible ions. also indicated Cr(VI) bound reduced Cr(III).

参考文章(35)
Dinesh Mohan, Charles U. Pittman Jr., Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water. Journal of Hazardous Materials. ,vol. 137, pp. 762- 811 ,(2006) , 10.1016/J.JHAZMAT.2006.06.060
Donghee Park, Yeoung-Sang Yun, Jong Moon Park, Comment on the Removal Mechanism of Hexavalent Chromium by Biomaterials or Biomaterial-Based Activated Carbons Industrial & Engineering Chemistry Research. ,vol. 45, pp. 2405- 2407 ,(2006) , 10.1021/IE0509387
J. Bouanda, L. Dupont, J. Dumonceau, M. Aplincourt, Use of a NICA–Donnan approach for analysis of proton binding to a lignocellulosic substrate extracted from wheat bran Analytical and Bioanalytical Chemistry. ,vol. 373, pp. 174- 182 ,(2002) , 10.1007/S00216-002-1305-Z
Eric Fourest, Bohumil Volesky, Contribution of Sulfonate Groups and Alginate to Heavy Metal Biosorption by the Dry Biomass of Sargassum fluitans Environmental Science & Technology. ,vol. 30, pp. 277- 282 ,(1996) , 10.1021/ES950315S
M. M. Figueira, B. Volesky, H. J. Mathieu, Instrumental Analysis Study of Iron Species Biosorption by Sargassum Biomass Environmental Science & Technology. ,vol. 33, pp. 1840- 1846 ,(1999) , 10.1021/ES981111P
J.H. Scofield, Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV Journal of Electron Spectroscopy and Related Phenomena. ,vol. 8, pp. 129- 137 ,(1976) , 10.1016/0368-2048(76)80015-1
D. A. Shirley, High-Resolution X-Ray Photoemission Spectrum of the Valence Bands of Gold Physical Review B. ,vol. 5, pp. 4709- 4714 ,(1972) , 10.1103/PHYSREVB.5.4709
Carlos Escudero, Núria Fiol, Isabel Villaescusa, Jean-Claude Bollinger, Effect of chromium speciation on its sorption mechanism onto grape stalks entrapped into alginate beads Arabian Journal of Chemistry. ,vol. 10, pp. S1293- S1302 ,(2017) , 10.1016/J.ARABJC.2013.03.011