Mild decarbonylation of transition metal carbonyls by rhodium(I) complexes

摘要: Abstract Transition metal carbonyls have been found to react with rhodium(I) complexes under mild conditions resultant transfer of carbonyl rhodium. Partial decarbonylation Mo(CO)6 and Fe(CO)5 gives Mo(PPh3)2(CO)4, Mo(Arene)(CO)3 (Arene = benzene, toluene or mesitylene, Fe(PPh3)(CO)4, Fe(PPh3)2(CO)3, Fe(Diene)(CO)3 (Diene butadiene isoprene). In the absence ligands capable stabilizing partially decarbonylated moieties goes completion. hexamethylphosphoramide exhaustive Cr(CO)6, Mo(CO)6, W(CO)6, Ni(CO)4 induced by [Rh(C8H14)2Cl]2 (C8H14 cyclooctene) proceeds homogeneously retention oxidation state rhodium (+1).