Easy synthesis of CaB2O4 via pyrolysis of calcium fructoborate
作者： Claudia Cecilia Wagner , Enrique José Baran
DOI: 10.1590/S1516-14392008000400020
关键词:
摘要: The investigation of the thermal behavior calcium fructoborate samples composition Ca(C6H10O6BO)2.3.5H 2O showed that CaB2O4 is generated as final solid pyrolysis residue. On basis these observations a new, very easy, synthetic procedure for preparation high purity this borate proposed. material was characterized by X ray powder diffractometry and IR spectroscopy.
sci-hub.se 参考文章(11)
Ulrich Schubert, Nicola Hüsing, Synthesis of Inorganic Materials Wiley-VCH. ,(2000)
W H Zachariasen, The Crystal Lattice of Calcium Metaborate ,(1931)
Alexander Frank . Wells, Structural inorganic chemistry ,(1945)
Douglas A Keszler, Borates for optical frequency conversion Current Opinion in Solid State & Materials Science. ,vol. 1, pp. 204- 211 ,(1996) , 10.1016/S1359-0286(96)80085-4
W. H. Zachariasen, The Crystal Lattice of Calcium Metaborate, CaB(2)O(4). Proceedings of the National Academy of Sciences of the United States of America. ,vol. 17, pp. 617- 619 ,(1931) , 10.1073/PNAS.17.11.617
Douglas A. Keszler, Synthesis, crystal chemistry, and optical properties of metal borates Current Opinion in Solid State & Materials Science. ,vol. 4, pp. 155- 162 ,(1999) , 10.1016/S1359-0286(99)00011-X
M. Marezio, H. A. Plettinger, W. H. Zachariasen, Refinement of the calcium metaborate structure Acta Crystallographica. ,vol. 16, pp. 390- 392 ,(1963) , 10.1107/S0365110X63001031
A. Rulmont, M. Almou, Vibrational spectra of metaborates with infinite chain structure: LiBO2, CaB2O4, SrB2O4 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 45, pp. 603- 610 ,(1989) , 10.1016/0584-8539(89)80013-3
C. N. R. Rao, Transition metal oxides ,(1995)
C. C. Wagner, V. Ferraresi Curotto, R. Pis Diez, E. J. Baran, Experimental and theoretical studies of calcium fructoborate. Biological Trace Element Research. ,vol. 122, pp. 64- 72 ,(2008) , 10.1007/S12011-007-8060-0