Spectral shape of in situ mass spectra of sympathetically cooled molecular ions

作者: Takashi Baba , Izumi Waki

DOI: 10.1063/1.1506005

关键词:

摘要: We formulated a model to reproduce the spectral shape of in situ mass spectra sympathetically cooled molecular ions trapped linear radio-frequency-quadrupole. The are by laser ions. spectrum is obtained observing fluorescence emitted from laser-cooled as we excite resonant motion trap. model, which uses pseudopotential and space-charge approach, reproduces molecules. suggests that variation density can produce in-trap kinetic excitation without loss excited

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