Recent Progress in the Chemistry of Metal Amidinates and Guanidinates: Syntheses, Catalysis and Materials
DOI: 10.1016/B978-0-12-407692-1.00002-3
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摘要: Abstract This review provides a comprehensive overview of the most recent progress in chemistry and applications metal complexes containing heteroallylic ligands such as amidinates guanidinates. Clearly, coordination guanidinates has reached state maturity continues to be highly popular area research. These ligand systems allow wealth variations modifications, making larger library available than cyclopentadienyl chemistry. Exciting results have been obtained years for almost any metallic elements Periodic Table. Truly remarkable developments include, example, cyclic amidinate-based silylenes stabilization metal–metal quadruply quintuple bonds by amidinate guanidinate ligands. The range homogeneous catalysis considerably broadened years. In materials science, alkyl-substituted are now well established volatile precursors variety ALD MOCVD processes. Without doubt related will continue produce exciting come.
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