Infrared and Raman spectra and external mode calculations for M2Cu2O5 semiconductors (M = In, Sc, Y and lanthanides from Tb to Lu)

作者: J. Hanuza , M. Andruszkiewicz , K. Hermanowicz , R. Horyń , J. Klamut

DOI: 10.1016/0584-8539(93)80066-J

关键词:

摘要: Abstract The room temperature FTIR transmission and Raman scattering spectra of M 2 Cu O 5 (M = In, Sc, Y, TbLu) semiconductors in the 30–700 cm −1 range are examined. A factor group analysis normal coordinate calculations have been performed to identify external modes. Urey—Bradley Force Field model potential energy distribution were applied phonon calculations. Y/Er Y/Gd exchange effects studied analysed terms 3+ ion translation energy.

参考文章(11)
H. Rosen, E. M. Engler, T. C. Strand, V. Y. Lee, D. Bethune, Raman study of lattice modes in the high-critical-temperature superconductor Y-Ba-Cu-O. Physical Review B. ,vol. 36, pp. 726- 728 ,(1987) , 10.1103/PHYSREVB.36.726
U. Lambert, W. Eysel, New Copper (II) — Rare Earth (III) Compounds I. Ternary Systems CuO-M2O3-TO2 Powder Diffraction. ,vol. 1, pp. 45- 50 ,(1986) , 10.1017/S088571560001157X
H.-R. Freund, Hk. M�ller-Buschbaum, Üer Oxocuprate. XXV Zur Kenntnis von In2Cu2O5 Zeitschrift für anorganische und allgemeine Chemie. ,vol. 441, pp. 103- 106 ,(1978) , 10.1002/ZAAC.19784410113
Noboru Kimizuka, Eiji Takayama, Shigeo Horiuchi, Akiji Yamamoto, Taketoshi Fujita, Ln2Cu2O5 compounds [Ln: Lu, Yb, Tm, Ho, Er, Dy, Tb, and Y] Journal of Solid State Chemistry. ,vol. 42, pp. 322- 324 ,(1982) , 10.1016/0022-4596(82)90009-3
Ray E. Kidder, Vibrational Analysis of Polyatomic Molecules. Ph.D. Thesis. ,(1951)
J. Hanuza, M. Andruszkiewicz, Z. Bukowski, R. Horyń, J. Klamut, Vibrational spectra and internal phonon calculations for the M2Cu2O5 binary oxides (M = In, Sc, Y or from Tb to Lu) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 46, pp. 691- 704 ,(1990) , 10.1016/0584-8539(90)80024-S
Z. V. Popović, C. Thomsen, M. Cardona, R. Liu, G. Stanišić, W. König, Infrared and Raman spectra of M2Cu2O5 (M=Y, Ho) European Physical Journal B. ,vol. 72, pp. 13- 16 ,(1988) , 10.1007/BF01313106
H.-R. Freund, Hk. Müller-Buschbaum, Über Oxocuprate, XXIV Zur Kenntnis von Lu2Cu2O5 und Sc2Cu2O5 / On Oxocuprates, XXIV About Lu2Cu2O5 and Sc2Cu2O5 Zeitschrift für Naturforschung B. ,vol. 32, pp. 1123- 1124 ,(1977) , 10.1515/ZNB-1977-1005
R. Troć, J. Klamut, Z. Bukowski, R. Horyń, J. Stȩpień-Damm, On the magnetic ordering in the R2Cu2O5 systems Physica B-condensed Matter. ,vol. 154, pp. 189- 196 ,(1989) , 10.1016/0921-4526(89)90067-7
J. Hanuza, L. Macalik, Polarized i.r. and Raman spectra of orthorhombic KLn(MoO4)2 crystals (Ln = Y, Dy, Ho, Er, Tm, Yb, Lu) Spectrochimica Acta Part A: Molecular Spectroscopy. ,vol. 38, pp. 61- 72 ,(1982) , 10.1016/0584-8539(82)80178-5