摘要: Criegee intermediates (CIs) ( 1 ) are the main in atmospheric reactions between ozone and organic molecules, resulting formation of free radicals, acids, carbonyl compounds, aerosols. Such contribute to local photochemical smog global climate change. Advances understanding chemistry CIs long remained elusive because these compounds could not be observed directly. On page 174 this issue, Su et al. 2 report direct detection a CI, on 177, Taatjes 3 describe CI kinetics data that yield key information about their impact atmosphere.
sciencemag.org
mpg.de
harvard.edu参考文章(12)
Luc Vereecken, Joseph S. Francisco, Theoretical studies of atmospheric reaction mechanisms in the troposphere Chemical Society Reviews. ,vol. 41, pp. 6259- 6293 ,(2012) , 10.1039/C2CS35070J
Craig A. Taatjes, Giovanni Meloni, Talitha M. Selby, Adam J. Trevitt, David L. Osborn, Carl J. Percival, Dudley E. Shallcross, Direct Observation of the Gas-Phase Criegee Intermediate (CH2OO) Journal of the American Chemical Society. ,vol. 130, pp. 11883- 11885 ,(2008) , 10.1021/JA804165Q
Dudley E. Shallcross, Carl J. Percival, David L. Osborn, Craig A. Taatjes, John M. Dyke, Edmond P. F. Lee, Daniel K. W. Mok, Spectroscopy of the simplest Criegee intermediate CH2OO: Simulation of the first bands in its electronic and photoelectron spectra Chemistry: A European Journal. ,vol. 18, pp. 12411- 12423 ,(2012) , 10.1002/CHEM.201200848
Y.-T. Su, Y.-H. Huang, H. A. Witek, Y.-P. Lee, Infrared Absorption Spectrum of the Simplest Criegee Intermediate CH2OO Science. ,vol. 340, pp. 174- 176 ,(2013) , 10.1126/SCIENCE.1234369
C. A. Taatjes, O. Welz, A. J. Eskola, J. D. Savee, A. M. Scheer, D. E. Shallcross, B. Rotavera, E. P. F. Lee, J. M. Dyke, D. K. W. Mok, D. L. Osborn, C. J. Percival, Direct measurements of conformer-dependent reactivity of the Criegee intermediate CH3CHOO Science. ,vol. 340, pp. 177- 180 ,(2013) , 10.1126/SCIENCE.1234689
L. Vereecken, H. Harder, A. Novelli, The reaction of Criegee intermediates with NO, RO2, and SO2, and their fate in the atmosphere Physical Chemistry Chemical Physics. ,vol. 14, pp. 14682- 14695 ,(2012) , 10.1039/C2CP42300F
Craig A. Taatjes, Oliver Welz, Arkke J. Eskola, John D. Savee, David L. Osborn, Edmond P. F. Lee, John M. Dyke, Daniel W. K. Mok, Dudley E. Shallcross, Carl J. Percival, Direct measurement of Criegee intermediate (CH2OO) reactions with acetone, acetaldehyde, and hexafluoroacetone Physical Chemistry Chemical Physics. ,vol. 14, pp. 10391- 10400 ,(2012) , 10.1039/C2CP40294G
O. Welz, J. D. Savee, D. L. Osborn, S. S. Vasu, C. J. Percival, D. E. Shallcross, C. A. Taatjes, Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2 Science. ,vol. 335, pp. 204- 207 ,(2012) , 10.1126/SCIENCE.1213229
R. L. Mauldin III, T. Berndt, M. Sipilä, P. Paasonen, T. Petäjä, S. Kim, T. Kurtén, F. Stratmann, V.-M. Kerminen, M. Kulmala, A new atmospherically relevant oxidant of sulphur dioxide Nature. ,vol. 488, pp. 193- 196 ,(2012) , 10.1038/NATURE11278
Torsten Berndt, Tuija Jokinen, Roy L. Mauldin, Tuukka Petäjä, Hartmut Herrmann, Heikki Junninen, Pauli Paasonen, Douglas R. Worsnop, Mikko Sipilä, Gas-Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO2 Journal of Physical Chemistry Letters. ,vol. 3, pp. 2892- 2896 ,(2012) , 10.1021/JZ301158U