Mimicking the Active Sites of Non-heme Iron Oxygenases on the Solid Supports of Catalysts: Formation of Immobilized Iron Complexes with Imidazolyl and Carboxylate Ligands

作者: Tomohiro Tsuruta , Tsubasa Yamazaki , Kazuki Watanabe , Yosuke Chiba , Akihiro Yoshida

DOI: 10.1246/CL.140937

关键词:

摘要: Iron oxygenases mimicking active sites have been constructed on the solid support by anchoring a bis(imidazolyl)borate ligand to carboxylate-functionalized SBA-15 type mesoporous silica gels. Initi...

参考文章(42)
Miquel Costas, Mark P. Mehn, Michael P. Jensen, Lawrence Que, Dioxygen Activation at Mononuclear Nonheme Iron Active Sites:  Enzymes, Models, and Intermediates Chemical Reviews. ,vol. 104, pp. 939- 986 ,(2004) , 10.1021/CR020628N
Eike Bauer, Recent Advances in Iron Catalysis in Organic Synthesis Current Organic Chemistry. ,vol. 12, pp. 1341- 1369 ,(2008) , 10.2174/138527208786241556
Nicholas J. Schoenfeldt, Zhenjuan Ni, Andrew W. Korinda, Randall J. Meyer, Justin M. Notestein, Manganese triazacyclononane oxidation catalysts grafted under reaction conditions on solid cocatalytic supports. Journal of the American Chemical Society. ,vol. 133, pp. 18684- 18695 ,(2011) , 10.1021/JA204761E
Tracy J. Terry, Geraud Dubois, Andrew Murphy, T. Daniel P. Stack, Site Isolation and Epoxidation Reactivity of a Templated Ferrous Bis(phenanthroline) Site in Porous Silica Angewandte Chemie. ,vol. 46, pp. 945- 947 ,(2007) , 10.1002/ANIE.200603423
Williamson N. Oloo, Yan Feng, Shyam Iyer, Sean Parmelee, Genqiang Xue, Lawrence Que, Cyclohexene as a substrate probe for the nature of the high-valent iron-oxo oxidant in Fe(TPA)-catalyzed oxidations New Journal of Chemistry. ,vol. 37, pp. 3411- 3415 ,(2013) , 10.1039/C3NJ00524K
Jun Nakazawa, Brian J. Smith, T. Daniel P. Stack, Discrete Complexes Immobilized onto Click-SBA-15 Silica: Controllable Loadings and the Impact of Surface Coverage on Catalysis Journal of the American Chemical Society. ,vol. 134, pp. 2750- 2759 ,(2012) , 10.1021/JA210400U
Debobrata Sheet, Partha Halder, Tapan Kanti Paine, Enhanced Reactivity of a Biomimetic Iron(II) α‐Keto Acid Complex through Immobilization on Functionalized Gold Nanoparticles Angewandte Chemie. ,vol. 52, pp. 13314- 13318 ,(2013) , 10.1002/ANIE.201305994
Maarten Merkx, Daniel A. Kopp, Matthew H. Sazinsky, Jessica L. Blazyk, Jens Müller, Stephen J. Lippard, Dioxygen Activation and Methane Hydroxylation by Soluble Methane Monooxygenase: A Tale of Two Irons and Three Proteins Angewandte Chemie International Edition. ,vol. 40, pp. 2782- 2807 ,(2001) , 10.1002/1521-3773(20010803)40:15<2782::AID-ANIE2782>3.0.CO;2-P
Olaf Cussó, Isaac Garcia-Bosch, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas, Asymmetric epoxidation with H2O2 by manipulating the electronic properties of non-heme iron catalysts. Journal of the American Chemical Society. ,vol. 135, pp. 14871- 14878 ,(2013) , 10.1021/JA4078446