CO, Formic Acid, and Methanol Oxidation in Acid Electrolytes–Mechanisms and Electrocatalysis

作者: Wolf Vielstich

DOI: 10.1002/9783527610426.BARD020502

关键词:

摘要: The sections in this article are Scope of the Chapter Basic Facts Thermodynamics, Open-circuit Potentials Reaction Pathways Bifunctional Mechanism Methanol Oxidation Oxidation CO, Formic Acid, and at Pt Metals Results via CV MSCV Carbon Monoxide Oxidation Methanol Oxidation Formic Acid Oxidation Study Adsorbates FTIRS Carbon Monoxide Formic Acid The Anodic Maximum Oxidation below 0.5 V Methanol Metal Alloys Binary Metal Catalysts CO Oxidation Oxidation Methanol Ad-atom Effects on Oxidation Surface Structure Electrocatalysis Ex Situ STM Images Taken during UHV Transfer Current Decay Smooth Surfaces Rate-determining Step Oxidation Instabilities – Oscillations Methanol, Carbon Monoxide General Conditions for Electrochemical Instabilities Potential Oxidation Current CO a Rotating Disc Nonelectrochemical Pathway

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