Efficient synthesis of cyclic P-stereogenic phosphinamides from acyclic chiral precursors via radical oxidative intramolecular aryl C-H phosphinamidation.
作者： Yuan-Hui Chen , Xu-Long Qin , Fu-She Han
DOI: 10.1039/C7CC02263H
关键词:
摘要: We present a highly efficient method for the synthesis of cyclic P-stereogenic phosphinamides via Ce(IV)-promoted radical oxidative aryl C–H phosphinamidation acyclic phosphinamides. The new protocol provides useful platform versatile various potentially compounds.
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