Chemoselectivity control in the reaction of a dinuclear chloro-bridged cyclopalladated complex with potassium diphenylphosphide
作者： Valeria A. Stepanova , Valery V. Dunina , Irina P. Smoliakova
DOI: 10.1016/J.JORGANCHEM.2010.10.020
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摘要: Abstract Reactions of KPPh2 with the dimeric cyclopalladated complex {Pd(N∩C)(μ-Cl)}2 1 derived from N,N-dimethylbenzylamine were studied using different reagent ratios, temperature, reaction time, concentrations and solvents. Complex 3, μ-Cl-μ-PPh2 analog 1, was obtained in 76% yield one-hour 1:1 ratio dimer THF at rt. ortho-(Diphenylphosphino)benzylamine 4 synthesized 58% by reacting 4.5 equiv. A possible mechanism aminophosphine formation is proposed on basis experimental data including 31P{1H} NMR spectra mixtures.
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sci-hub.se 参考文章(55)
Jairton Dupont, Michel Pfeffer, Palladacycles : synthesis, characterization and applications Wiley-VCH. ,(2008)
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
Jaime G. Fierro-Arias, Rocío Redón, Juventino J. García, Simón Hernández-Ortega, Rubén A. Toscano, David Morales-Morales, Pd catalyzed Heck reaction with the catalytic system [Pd(Ph2PC6H4-2-(CH2NMe2))(SRF)2] Journal of Molecular Catalysis A: Chemical. ,vol. 233, pp. 17- 27 ,(2005) , 10.1016/J.MOLCATA.2005.02.007
Antony J. Hannaford, Peter W. G. Smith, Austin R. Tatchell, Brian S. Furniss, Vogel's Textbook of Practical Organic Chemistry ,(1996)
Jairton Dupont, Crestina S. Consorti, John Spencer, The potential of palladacycles: more than just precatalysts Chemical Reviews. ,vol. 105, pp. 2527- 2571 ,(2005) , 10.1021/CR030681R
Richard A. Jones, Anthony L. Stuart, Thomas C. Wright, Isolation and x-ray structure of bis[(tetrahydrofuran)(.mu.2-di-tert-butylphosphido)(.mu.3-di-tert-butylphosphido)dilithium] ([Li2(.mu.3-tert-Bu2P)(.mu.2-tert-Bu2P)(C4H8O)]2) containing a staggered, planar lithium (Li4) unit. The first structurally characterized alkali metal diorganophosphide Journal of the American Chemical Society. ,vol. 105, pp. 7459- 7460 ,(1983) , 10.1021/JA00363A051
Corina Scriban, David S. Glueck, Antonio G. DiPasquale, Arnold L. Rheingold, Chiral Platinum Duphos Terminal Phosphido Complexes: Synthesis, Structure, Phosphido Transfer, and Ligand Behavior Organometallics. ,vol. 25, pp. 5435- 5448 ,(2006) , 10.1021/OM060614Y
Franco Cecconi, Carlo A. Ghilardi, Stefano Midollini, Simonetta Moneti, Annabella Orlandini, Giancarlo Scapacci, Dechlorination of ClPEt2 by (np3)Pt(PPh3) (np3N(CH2CH2PPh2)3): synthesis and characterization of [(np3)Pt(PEt2)](BPh4) and [(np3)Pt(PHEt2)](BPh4)2 Inorganica Chimica Acta. ,vol. 189, pp. 105- 110 ,(1991) , 10.1016/S0020-1693(00)80395-3
Corina Scriban, Denyce K. Wicht, David S. Glueck, Lev N. Zakharov, James A. Golen, Arnold L. Rheingold, Platinum(II) Phosphido Complexes as Metalloligands. Structural and Spectroscopic Consequences of Conversion from Terminal to Bridging Coordination Organometallics. ,vol. 25, pp. 3370- 3378 ,(2006) , 10.1021/OM050149P
Roberto Giannandrea, Piero Mastrorilli, Cosimo Francesco Nobile, Massimo Dilonardo, Reaction of nickel(II) and palladium(II) with tetraphenyldiphosphine Inorganica Chimica Acta. ,vol. 249, pp. 237- 238 ,(1996) , 10.1016/0020-1693(96)05086-4